Application of the Flory-Huggins theory to the solubility of solids in glyceryl trioleate

Cary T. Chiou, Milton Manes

研究成果: Article同行評審

18 引文 斯高帕斯(Scopus)

摘要

The conventional thermodynamic deviation for ideal solid-liquid solubilities is modified by substituting the Flory-Huggins model for Raoult's law. A comparison of published data for eleven solides in glyceryl trioleate with the predictions of the conventional and modified equations shows that the significantly higher athermal solubilities from the modified equation are in much better agreement with the experimental data. This suggests that discrepancies between the data and the predictions of the conventional model for ideal systems result from the inappropriate use of Raoult's law for systems with significant solute-solvent size disparity rather than from specific interactions.

原文English
頁(從 - 到)243-246
頁數4
期刊Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
82
發行號1
DOIs
出版狀態Published - 1986 一月 1

All Science Journal Classification (ASJC) codes

  • 化學 (全部)

指紋

深入研究「Application of the Flory-Huggins theory to the solubility of solids in glyceryl trioleate」主題。共同形成了獨特的指紋。

引用此