Atom-Dependent Edge-Enhanced Second-Harmonic Generation on MoS2 Monolayers

Kuang-I Lin, Yen Hung Ho, Shu Bai Liu, Jian Jhih Ciou, Bo Ting Huang, Christopher Chen, Han Ching Chang, Chien Liang Tu, Chang Hsiao Chen

研究成果: Article

10 引文 (Scopus)

摘要

Edge morphology and lattice orientation of single-crystal molybdenum disulfide (MoS2) monolayers, a transition metal dichalcogenide (TMD), possessing a triangular shape with different edges grown by chemical vapor deposition are characterized by atomic force microscopy and transmission electron microscopy. Multiphoton laser scanning microscopy is utilized to study one-dimensional atomic edges of MoS2 monolayers with localized midgap electronic states, which result in greatly enhanced optical second-harmonic generation (SHG). Microscopic S-zigzag edge and S-Mo Klein edge (bare Mo atoms protruding from a S-zigzag edge) terminations and the edge-atom dependent resonance energies can therefore be deduced based on SHG images. Theoretical calculations based on density functional theory clearly explain the lower energy of the S-zigzag edge states compared to the corresponding S-Mo Klein edge states. Characterization of the atomic-scale variation of edge-enhanced SHG is a step forward in this full-optical and high-yield technique of atomic-layer TMDs.

原文English
頁(從 - 到)793-797
頁數5
期刊Nano letters
18
發行號2
DOIs
出版狀態Published - 2018 二月 14

指紋

Harmonic generation
Monolayers
harmonic generations
Atoms
atoms
Electronic states
Crystal lattices
Crystal orientation
Molybdenum
Transition metals
Density functional theory
Chemical vapor deposition
Atomic force microscopy
Microscopic examination
Single crystals
Transmission electron microscopy
Scanning
Lasers
molybdenum disulfides
transition metals

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

引用此文

Lin, K-I., Ho, Y. H., Liu, S. B., Ciou, J. J., Huang, B. T., Chen, C., ... Chen, C. H. (2018). Atom-Dependent Edge-Enhanced Second-Harmonic Generation on MoS2 Monolayers. Nano letters, 18(2), 793-797. https://doi.org/10.1021/acs.nanolett.7b04006
Lin, Kuang-I ; Ho, Yen Hung ; Liu, Shu Bai ; Ciou, Jian Jhih ; Huang, Bo Ting ; Chen, Christopher ; Chang, Han Ching ; Tu, Chien Liang ; Chen, Chang Hsiao. / Atom-Dependent Edge-Enhanced Second-Harmonic Generation on MoS2 Monolayers. 於: Nano letters. 2018 ; 卷 18, 編號 2. 頁 793-797.
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abstract = "Edge morphology and lattice orientation of single-crystal molybdenum disulfide (MoS2) monolayers, a transition metal dichalcogenide (TMD), possessing a triangular shape with different edges grown by chemical vapor deposition are characterized by atomic force microscopy and transmission electron microscopy. Multiphoton laser scanning microscopy is utilized to study one-dimensional atomic edges of MoS2 monolayers with localized midgap electronic states, which result in greatly enhanced optical second-harmonic generation (SHG). Microscopic S-zigzag edge and S-Mo Klein edge (bare Mo atoms protruding from a S-zigzag edge) terminations and the edge-atom dependent resonance energies can therefore be deduced based on SHG images. Theoretical calculations based on density functional theory clearly explain the lower energy of the S-zigzag edge states compared to the corresponding S-Mo Klein edge states. Characterization of the atomic-scale variation of edge-enhanced SHG is a step forward in this full-optical and high-yield technique of atomic-layer TMDs.",
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Lin, K-I, Ho, YH, Liu, SB, Ciou, JJ, Huang, BT, Chen, C, Chang, HC, Tu, CL & Chen, CH 2018, 'Atom-Dependent Edge-Enhanced Second-Harmonic Generation on MoS2 Monolayers', Nano letters, 卷 18, 編號 2, 頁 793-797. https://doi.org/10.1021/acs.nanolett.7b04006

Atom-Dependent Edge-Enhanced Second-Harmonic Generation on MoS2 Monolayers. / Lin, Kuang-I; Ho, Yen Hung; Liu, Shu Bai; Ciou, Jian Jhih; Huang, Bo Ting; Chen, Christopher; Chang, Han Ching; Tu, Chien Liang; Chen, Chang Hsiao.

於: Nano letters, 卷 18, 編號 2, 14.02.2018, p. 793-797.

研究成果: Article

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AU - Ho, Yen Hung

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AU - Ciou, Jian Jhih

AU - Huang, Bo Ting

AU - Chen, Christopher

AU - Chang, Han Ching

AU - Tu, Chien Liang

AU - Chen, Chang Hsiao

PY - 2018/2/14

Y1 - 2018/2/14

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