Au@Cu2O core@shell nanocrystals as dual-functional catalysts for sustainable environmental applications

Ming Yu Kuo, Chih Feng Hsiao, Yi Hsuan Chiu, Ting Hsuan Lai, Mei Jing Fang, Jhen Yang Wu, Jhih Wei Chen, Chung Lin Wu, Kung Hwa Wei, Hsin Chieh Lin, Yung Jung Hsu

研究成果: Article同行評審

45 引文 斯高帕斯(Scopus)

摘要

This work reports the synthesis of Au@Cu2O core@shell nanocrystals with controllable shell thicknesses and demonstrates their use as the dual-functional catalyst that can continuously operate under illumination and darkness conditions for efficient E. coli inactivation. On account of the peroxidase mimics of the Au core and Fenton reactivity of the Cu2O shell, the Au@Cu2O nanocrystals exhibit intrinsic peroxidase-like property with the reaction kinetics in accordance with the typical Michaelis–Menten mechanism. On the other hand, time-resolved photoluminescence spectra suggest the prevalence of pronounced charge separation for Au@Cu2O nanocrystals, an important advantage that is favourable for photocatalysis. By combining the photocatalytic capability with the peroxidase mimics features, Au@Cu2O nanocrystals can perform practical photocatalytic decomposition of E. coli under visible light illumination but still show vital activity towards E. coli inactivation after light illumination was turned off. The current study delivers a new catalyst configuration by exploiting the multiple functionalities of nanosized Au and Cu2O for advanced environmental and energy conversion applications.

原文English
頁(從 - 到)499-506
頁數8
期刊Applied Catalysis B: Environmental
242
DOIs
出版狀態Published - 2019 三月

All Science Journal Classification (ASJC) codes

  • 催化
  • 環境科學 (全部)
  • 製程化學與技術

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