Biochar loaded with CoFe2O4 enhances the formation of high-valent Fe(IV) and Co(IV) and oxygen vacancy in the peracetic acid activation system for enhanced antibiotic degradation

Shuo Li, Yingnan Liu, Heshan Zheng, Junfeng Niu, Yoong Kit Leong, Duu Jong Lee, Jo Shu Chang

研究成果: Article同行評審

4 引文 斯高帕斯(Scopus)

摘要

Corn straw and sludge-derived biochar composite (BC) loaded with CoFe2O4 was successfully prepared to activate peracetic acid (PAA) for efficient degradation of tetracycline hydrochloride (TCH). Within 60 s, 96 % TCH removal efficiency was achieved through a non-free radical degradation pathway, primarily driven by singlet oxygen (1O2). The mechanism involves the electron-rich groups on the biochar surface, which facilitate the cleavage of the PAA O–O bond to generate •O2/1O2 and provide electrons to induce the formation of high-valent Fe(IV) and Co(IV). The oxygen vacancies on the surface of the CoFe2O4-loaded biochar composite (CFB-2) contribute partially to 1O2 production through their transformation into a metastable intermediate with dissolved oxygen. Moreover, elevated temperatures further enhance PAA activation by CFB-2, leading to increased reactive oxygen species (ROS) production through PAA decomposition, thereby promoting TCH removal. This study offers new insights into the catalysis of metal-loaded biochar for efficient TCH degradation via non-free radical generation.

原文English
文章編號129536
期刊Bioresource technology
387
DOIs
出版狀態Published - 2023 11月

All Science Journal Classification (ASJC) codes

  • 生物工程
  • 環境工程
  • 可再生能源、永續發展與環境
  • 廢物管理和處置

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