Bowl-shaped fragments of C70 or higher fullerenes: Synthesis, structural analysis, and inversion dynamics

Tsun Cheng Wu, Min Kuan Chen, Yen Wei Lee, Ming Yu Kuo, Yao-Ting Wu

研究成果: Article

54 引文 斯高帕斯(Scopus)

摘要

Super bowl: Fragments of C70 or higher fullerenes were easily prepared from 1,8-bis(arylethynyl)naphthalenes. The curved structures were identified by X-ray crystallography. These rigid bowl-shaped molecules have a deep bowl depth (approximately 2.30 Å) and their bowl inversions proceed via an S-shaped transition structure with a very high inversion barrier (approximately 80 kcal mol-1).

原文English
頁(從 - 到)1289-1293
頁數5
期刊Angewandte Chemie - International Edition
52
發行號4
DOIs
出版狀態Published - 2013 一月 21

    指紋

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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