Bowl-shaped fragments of C70 or higher fullerenes: Synthesis, structural analysis, and inversion dynamics

Tsun Cheng Wu; Min Kuan Chen; Yen Wei Lee; Ming Yu Kuo; Yao Ting Wu

doi:10.1002/anie.201208200

Bowl-shaped fragments of C₇₀ or higher fullerenes: Synthesis, structural analysis, and inversion dynamics

Tsun Cheng Wu
, Min Kuan Chen
, Yen Wei Lee
, Ming Yu Kuo
, Yao Ting Wu

化學系

研究成果: Article › 同行評審

94 引文斯高帕斯（Scopus）

摘要

Super bowl: Fragments of C₇₀ or higher fullerenes were easily prepared from 1,8-bis(arylethynyl)naphthalenes. The curved structures were identified by X-ray crystallography. These rigid bowl-shaped molecules have a deep bowl depth (approximately 2.30 Å) and their bowl inversions proceed via an S-shaped transition structure with a very high inversion barrier (approximately 80 kcal mol^-1).

原文	English
頁（從 - 到）	1289-1293
頁數	5
期刊	Angewandte Chemie - International Edition
卷	52
發行號	4
DOIs	https://doi.org/10.1002/anie.201208200
出版狀態	Published - 2013 1月 21

All Science Journal Classification (ASJC) codes

催化
一般化學

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10.1002/anie.201208200

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Bowl-shaped fragments of C70 or higher fullerenes: Synthesis, structural analysis, and inversion dynamics

摘要

All Science Journal Classification (ASJC) codes

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指紋

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Bowl-shaped fragments of C₇₀ or higher fullerenes: Synthesis, structural analysis, and inversion dynamics