Catalytic reduction of hydrazine to ammonia by a vanadium thiolate complex

Wei Cheng Chu, Chi Chin Wu, Hua-Fen Hsu

研究成果: Article同行評審

40 引文 斯高帕斯(Scopus)

摘要

Vanadium(III) thiolate complexes, [V(PS3″)(Cl)]- [1a; PS3″ = P(C6H3-3-Me3Si-2-S) 33-] and [V(PS3′)(Cl)]- [1b; PS3′ = P(C6H3-5-Me-2-S)33-], were synthesized and characterized. Complex 1a serves as a precursor for the catalytic reduction of hydrazine to ammonia. The spectroscopic and electrochemical studies indicate that hydrazine is bound and activated in a VII state.

原文English
頁(從 - 到)3164-3166
頁數3
期刊Inorganic Chemistry
45
發行號8
DOIs
出版狀態Published - 2006 4月 17

All Science Journal Classification (ASJC) codes

  • 物理與理論化學
  • 無機化學

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