Cerium salts in the oxidative free radical reactions between 2-amino-1,4-naphthoquinones and β-dicarbonyl compounds

Chih Chung Tseng, Yi Lung Wu, Che Ping Chuang

研究成果: Article同行評審

68 引文 斯高帕斯(Scopus)

摘要

The oxidative free radical reactions between 2-amino-1,4-naphthoquinones and β-dicarbonyl compounds mediated by cerium(IV) salts are described. In contrast to those mediated by manganese(III) acetate, the cerium(IV) mediated free radical reaction provides a novel method for the synthesis of benzo[f]indole-4,9-diones exclusively. This high selectivity is due to the strong oxaphilicity of the cerium salts.

原文English
頁(從 - 到)7625-7633
頁數9
期刊Tetrahedron
58
發行號38
DOIs
出版狀態Published - 2002 九月 16

All Science Journal Classification (ASJC) codes

  • 生物化學
  • 藥物發現
  • 有機化學

指紋

深入研究「Cerium salts in the oxidative free radical reactions between 2-amino-1,4-naphthoquinones and β-dicarbonyl compounds」主題。共同形成了獨特的指紋。

引用此