摘要
The oxidative free radical reactions between 2-amino-1,4-naphthoquinones and β-dicarbonyl compounds mediated by cerium(IV) salts are described. In contrast to those mediated by manganese(III) acetate, the cerium(IV) mediated free radical reaction provides a novel method for the synthesis of benzo[f]indole-4,9-diones exclusively. This high selectivity is due to the strong oxaphilicity of the cerium salts.
原文 | English |
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頁(從 - 到) | 7625-7633 |
頁數 | 9 |
期刊 | Tetrahedron |
卷 | 58 |
發行號 | 38 |
DOIs | |
出版狀態 | Published - 2002 9月 16 |
All Science Journal Classification (ASJC) codes
- 生物化學
- 藥物發現
- 有機化學