TY - JOUR
T1 - Cobalt Catalysts Derived from Layered Double Hydroxide/g-C3N4 Composite in the Hydrogenation of γ-Valerolactone into 1,4-Pentanediol
AU - Lin, Yu Chuan
AU - Hsieh, Chou Hsun
N1 - Funding Information:
This study was supported by the Ministry of Science and Technology (Projects 109-2628-E-006-011-MY3, 110-2221-E-006-165-MY3, 110-2923-E-006-005-MY3, and 110-2927-I-006-506) and the Higher Education Sprout Project, Ministry of Education to the Headquarters of University Advancement at National Cheng Kung University (NCKU). The authors also appreciate the use of an elemental analyzer (EA000600, MOST 110-2731-M-006-001) belonging to the Core Facility Center of National Cheng Kung University. The authors thanks Debayan Mazumdar (NCKU) for the language editing.
Funding Information:
This study was supported by the Ministry of Science and Technology (Projects 109-2628-E-006-011-MY3, 110-2221-E-006-165-MY3, 110-2923-E-006-005-MY3, and 110-2927-I-006-506) and the Higher Education Sprout Project, Ministry of Education to the Headquarters of University Advancement at National Cheng Kung University (NCKU). The authors also appreciate the use of an elemental analyzer (EA000600, MOST 110-2731-M-006-001) belonging to the Core Facility Center of National Cheng Kung University. The authors thanks Debayan Mazumdar (NCKU) for the language editing.
Publisher Copyright:
© 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.
PY - 2023/3
Y1 - 2023/3
N2 - Co-based catalysts were derived from CoAl-layered double hydroxide (LDH), LDH/melamine, LDH/activated carbon, and LDH/g-C3N4. The use of these catalysts for the hydrogenation of γ-valerolactone into 1,4-pentanediol was investigated. The catalyst derived from CoAl-LDH/g-C3N4 contained higher concentrations of strong Brønsted acid, Lewis acid (Coδ+, δ > 2), and Lewis base (N with a lone pair of electrons) sites, resulting in improved turnover frequency.
AB - Co-based catalysts were derived from CoAl-layered double hydroxide (LDH), LDH/melamine, LDH/activated carbon, and LDH/g-C3N4. The use of these catalysts for the hydrogenation of γ-valerolactone into 1,4-pentanediol was investigated. The catalyst derived from CoAl-LDH/g-C3N4 contained higher concentrations of strong Brønsted acid, Lewis acid (Coδ+, δ > 2), and Lewis base (N with a lone pair of electrons) sites, resulting in improved turnover frequency.
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U2 - 10.1007/s10563-022-09383-7
DO - 10.1007/s10563-022-09383-7
M3 - Article
AN - SCOPUS:85141751233
SN - 1571-1013
VL - 27
SP - 20
EP - 28
JO - Catalysis Surveys from Asia
JF - Catalysis Surveys from Asia
IS - 1
ER -