Complexation and electronic communication between corannulene-based buckybowls and a curved truxene-TTF donor

María Gallego, Joaquín Calbo, Rafael M.Krick Calderon, Paula Pla, Ya Chu Hsieh, Emilio M. Pérez, Yao Ting Wu, Enrique Ortí, Dirk M. Guldi, Nazario Martín

研究成果: Article

13 引文 (Scopus)

摘要

The association behavior of an electron-donating, bowl-shaped, truxene-based tetrathiafulvalene (truxTTF) with two corannulene-based fullerene fragments, C32H12 and C38H14, is investigated in several solvents. Formation of 1:1 complexes is followed by absorption titrations and complemented by density functional theory (DFT) calculations. The binding constants are in the range logKa=2.9–3.5. DFT calculations reveal that the most stable arrangement is the conformation in which the 1,3-dithiole ring of truxTTF is placed inside the concave cavity of the corannulene derivative. This arrangement is confirmed experimentally by NMR measurements, and implies that a combination of π–π and CH–π interactions is the driving force for association. Timedependent DFT calculations reproduce the experimental UV/ Vis titrations and provide a detailed understanding of the spectral changes observed. Femtosecond transient absorption studies reveal the processes occurring after photoexcitation of either C32H12 or C38H14 and their supramolecular associates with truxTTF. In the case of truxTTF·C38H14, photoexcitation yields the charge-separated state truxTTFC+·C38H14·-with a lifetime of approximately 160 ps.

原文English
頁(從 - 到)3666-3673
頁數8
期刊Chemistry - A European Journal
23
發行號15
DOIs
出版狀態Published - 2017 一月 1

指紋

Complexation
Density functional theory
Photoexcitation
Titration
Communication
Association reactions
Fullerenes
Conformations
Nuclear magnetic resonance
Derivatives
Electrons
corannulene
tetrathiafulvalene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Organic Chemistry

引用此文

Gallego, M., Calbo, J., Calderon, R. M. K., Pla, P., Hsieh, Y. C., Pérez, E. M., ... Martín, N. (2017). Complexation and electronic communication between corannulene-based buckybowls and a curved truxene-TTF donor. Chemistry - A European Journal, 23(15), 3666-3673. https://doi.org/10.1002/chem.201604921
Gallego, María ; Calbo, Joaquín ; Calderon, Rafael M.Krick ; Pla, Paula ; Hsieh, Ya Chu ; Pérez, Emilio M. ; Wu, Yao Ting ; Ortí, Enrique ; Guldi, Dirk M. ; Martín, Nazario. / Complexation and electronic communication between corannulene-based buckybowls and a curved truxene-TTF donor. 於: Chemistry - A European Journal. 2017 ; 卷 23, 編號 15. 頁 3666-3673.
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abstract = "The association behavior of an electron-donating, bowl-shaped, truxene-based tetrathiafulvalene (truxTTF) with two corannulene-based fullerene fragments, C32H12 and C38H14, is investigated in several solvents. Formation of 1:1 complexes is followed by absorption titrations and complemented by density functional theory (DFT) calculations. The binding constants are in the range logKa=2.9–3.5. DFT calculations reveal that the most stable arrangement is the conformation in which the 1,3-dithiole ring of truxTTF is placed inside the concave cavity of the corannulene derivative. This arrangement is confirmed experimentally by NMR measurements, and implies that a combination of π–π and CH–π interactions is the driving force for association. Timedependent DFT calculations reproduce the experimental UV/ Vis titrations and provide a detailed understanding of the spectral changes observed. Femtosecond transient absorption studies reveal the processes occurring after photoexcitation of either C32H12 or C38H14 and their supramolecular associates with truxTTF. In the case of truxTTF·C38H14, photoexcitation yields the charge-separated state truxTTFC+·C38H14·-with a lifetime of approximately 160 ps.",
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Gallego, M, Calbo, J, Calderon, RMK, Pla, P, Hsieh, YC, Pérez, EM, Wu, YT, Ortí, E, Guldi, DM & Martín, N 2017, 'Complexation and electronic communication between corannulene-based buckybowls and a curved truxene-TTF donor', Chemistry - A European Journal, 卷 23, 編號 15, 頁 3666-3673. https://doi.org/10.1002/chem.201604921

Complexation and electronic communication between corannulene-based buckybowls and a curved truxene-TTF donor. / Gallego, María; Calbo, Joaquín; Calderon, Rafael M.Krick; Pla, Paula; Hsieh, Ya Chu; Pérez, Emilio M.; Wu, Yao Ting; Ortí, Enrique; Guldi, Dirk M.; Martín, Nazario.

於: Chemistry - A European Journal, 卷 23, 編號 15, 01.01.2017, p. 3666-3673.

研究成果: Article

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T1 - Complexation and electronic communication between corannulene-based buckybowls and a curved truxene-TTF donor

AU - Gallego, María

AU - Calbo, Joaquín

AU - Calderon, Rafael M.Krick

AU - Pla, Paula

AU - Hsieh, Ya Chu

AU - Pérez, Emilio M.

AU - Wu, Yao Ting

AU - Ortí, Enrique

AU - Guldi, Dirk M.

AU - Martín, Nazario

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The association behavior of an electron-donating, bowl-shaped, truxene-based tetrathiafulvalene (truxTTF) with two corannulene-based fullerene fragments, C32H12 and C38H14, is investigated in several solvents. Formation of 1:1 complexes is followed by absorption titrations and complemented by density functional theory (DFT) calculations. The binding constants are in the range logKa=2.9–3.5. DFT calculations reveal that the most stable arrangement is the conformation in which the 1,3-dithiole ring of truxTTF is placed inside the concave cavity of the corannulene derivative. This arrangement is confirmed experimentally by NMR measurements, and implies that a combination of π–π and CH–π interactions is the driving force for association. Timedependent DFT calculations reproduce the experimental UV/ Vis titrations and provide a detailed understanding of the spectral changes observed. Femtosecond transient absorption studies reveal the processes occurring after photoexcitation of either C32H12 or C38H14 and their supramolecular associates with truxTTF. In the case of truxTTF·C38H14, photoexcitation yields the charge-separated state truxTTFC+·C38H14·-with a lifetime of approximately 160 ps.

AB - The association behavior of an electron-donating, bowl-shaped, truxene-based tetrathiafulvalene (truxTTF) with two corannulene-based fullerene fragments, C32H12 and C38H14, is investigated in several solvents. Formation of 1:1 complexes is followed by absorption titrations and complemented by density functional theory (DFT) calculations. The binding constants are in the range logKa=2.9–3.5. DFT calculations reveal that the most stable arrangement is the conformation in which the 1,3-dithiole ring of truxTTF is placed inside the concave cavity of the corannulene derivative. This arrangement is confirmed experimentally by NMR measurements, and implies that a combination of π–π and CH–π interactions is the driving force for association. Timedependent DFT calculations reproduce the experimental UV/ Vis titrations and provide a detailed understanding of the spectral changes observed. Femtosecond transient absorption studies reveal the processes occurring after photoexcitation of either C32H12 or C38H14 and their supramolecular associates with truxTTF. In the case of truxTTF·C38H14, photoexcitation yields the charge-separated state truxTTFC+·C38H14·-with a lifetime of approximately 160 ps.

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