Critical Exponents for Off-Lattice Gelation of Polymer Chains

Liang-Yuan Shy, Y. K. Leung, B. E. Eichinger

研究成果: Article同行評審

48 引文 斯高帕斯(Scopus)

摘要

The random polycondensation of telechelic linear chains cured with tri- and tetrafunctional cross-linkers has been simulated. Calculations are done for both bulk and solution reactions; critical points are located by different methods, with results in good agreement with experiment. Critical exponents 0 and 7 vary from system to system, with average values 0 = 0.300 ± 0.024 and γ=1.77±0.16. The average value C_/C+ = 13.58 ± 3.50 is slightly larger than that from standard percolation.

原文English
頁(從 - 到)983-986
頁數4
期刊Macromolecules
18
發行號5
DOIs
出版狀態Published - 1985 一月 1

All Science Journal Classification (ASJC) codes

  • 有機化學
  • 聚合物和塑料
  • 無機化學
  • 材料化學

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