Crystal chemistry of HgBa2CaCu2O8+δ and HgBa2Ca2Cu3O8+δ single-crystal x-ray diffraction results

L. W. Finger, R. M. Hazen, R. T. Downs, R. L. Meng, C. W. Chu

研究成果: Article同行評審

63 引文 斯高帕斯(Scopus)

摘要

Crystal structures of HgBa2CaCu2O6+δ (Hg-1212) and HgBa2Ca2Cu3O8+δ (Hg-1223) have been determined on single crystals at room temperature conditions by X-ray diffraction techniques. Both tetragonal specimens are isomorphous with compounds in the Tl-Ba-Ca-Cu-O system. We observe excess oxygen in both samples on two sites near the z=0 plane: at ( 1 200) and close to ( 1 2, 0.4, 0) - but no oxygen at ( 1 2 1 20) as reported in earlier studies. Refined Hg occupancies for both samples indicate a substitution of Cu for Hg of more than ten percent. If the substitution of Cu for Hg and excess O at ( 1 200) are coupled, then the effect is to insert a perovskite-like six-coordinated copper site at (000). No evidence was found for a split atom at the barium sites in these compounds.

原文English
頁(從 - 到)216-221
頁數6
期刊Physica C: Superconductivity and its applications
226
發行號3-4
DOIs
出版狀態Published - 1994 6月 10

All Science Journal Classification (ASJC) codes

  • 電子、光磁材料
  • 凝聚態物理學
  • 能源工程與電力技術
  • 電氣與電子工程

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