摘要
Two fluorite-type solid solutions of Pb//1// minus //yBi//yF//2//30 //y(y approximately less than 0. 5) and Pb//1// minus //yBi//yO//0//. //5//yF//2(y greater than 0. 8) were synthesized hydrothermally from alpha -PbF//2 and beta -BiF//3 at 250 degree to 500 degree C for 4 h to 14 days under 100 MPa using sealed Pt-capsules. The water molecules and/or hydroxyl ion (OH** minus ) in the products synthesized hydrothermally were not detected by Fourier transform infrared spectrophotometry. Pb//1// minus //yBi//yF//2// plus //y solid solution ( beta -PbF//2ss) was synthesized at 400 degree C from compositions containing 0 to 50 mol% BiF//3.
原文 | English |
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頁(從 - 到) | 191-196 |
頁數 | 6 |
期刊 | Yogyo Kyokai Shi/Journal of the Ceramic Society of Japan |
卷 | 95 |
發行號 | 2 pt 2 |
出版狀態 | Published - 1987 1月 1 |
All Science Journal Classification (ASJC) codes
- 工程 (全部)