Cubic phase stabilization of Barium titanate nanorods by rapid quenching technique

Aswaghosh Loganathan, Divinah Manoharan, Victor Jaya Nesamony

研究成果: Article同行評審

3 引文 斯高帕斯(Scopus)

摘要

Stabilization of high temperature cubic phase of BaTiO3 at room temperature is established by rapid quenching of the surfactant assisted sonochemically synthesized BaTiO3 after calcination for 2 h at 800 °C. The quenched BaTiO3 is stabilized to cubic phase at room temperature in contrast to the BaTiO3 obtained by normal cooling at a rate of 1 °C/min, which exists in the tetragonal phase at room temperature. BaTiO3 prepared by the same synthetic procedure but two different heat treatment methods possesses almost similar morphology (i.e.) 1-dimensional nanorod structure but with different aspect ratio. Quenching prevents the low temperature phase transformation c→t from occurring by providing a narrow window of time in which the reaction is both thermodynamically favourable and kinetically accessible.

原文English
頁(從 - 到)305-307
頁數3
期刊Materials Letters
186
DOIs
出版狀態Published - 2017 1月 1

All Science Journal Classification (ASJC) codes

  • 材料科學(全部)
  • 凝聚態物理學
  • 材料力學
  • 機械工業

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