摘要
Stabilization of high temperature cubic phase of BaTiO3 at room temperature is established by rapid quenching of the surfactant assisted sonochemically synthesized BaTiO3 after calcination for 2 h at 800 °C. The quenched BaTiO3 is stabilized to cubic phase at room temperature in contrast to the BaTiO3 obtained by normal cooling at a rate of 1 °C/min, which exists in the tetragonal phase at room temperature. BaTiO3 prepared by the same synthetic procedure but two different heat treatment methods possesses almost similar morphology (i.e.) 1-dimensional nanorod structure but with different aspect ratio. Quenching prevents the low temperature phase transformation c→t from occurring by providing a narrow window of time in which the reaction is both thermodynamically favourable and kinetically accessible.
| 原文 | English |
|---|---|
| 頁（從 - 到） | 305-307 |
| 頁數 | 3 |
| 期刊 | Materials Letters |
| 卷 | 186 |
| DOIs | |
| 出版狀態 | Published - 2017 一月 1 |
指紋
All Science Journal Classification (ASJC) codes
- Materials Science(all)
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering
引用此文
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Cubic phase stabilization of Barium titanate nanorods by rapid quenching technique. / Loganathan, Aswaghosh; Manoharan, Divinah; Nesamony, Victor Jaya.
於: Materials Letters, 卷 186, 01.01.2017, p. 305-307.研究成果: Article
TY - JOUR
T1 - Cubic phase stabilization of Barium titanate nanorods by rapid quenching technique
AU - Loganathan, Aswaghosh
AU - Manoharan, Divinah
AU - Nesamony, Victor Jaya
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Stabilization of high temperature cubic phase of BaTiO3 at room temperature is established by rapid quenching of the surfactant assisted sonochemically synthesized BaTiO3 after calcination for 2 h at 800 °C. The quenched BaTiO3 is stabilized to cubic phase at room temperature in contrast to the BaTiO3 obtained by normal cooling at a rate of 1 °C/min, which exists in the tetragonal phase at room temperature. BaTiO3 prepared by the same synthetic procedure but two different heat treatment methods possesses almost similar morphology (i.e.) 1-dimensional nanorod structure but with different aspect ratio. Quenching prevents the low temperature phase transformation c→t from occurring by providing a narrow window of time in which the reaction is both thermodynamically favourable and kinetically accessible.
AB - Stabilization of high temperature cubic phase of BaTiO3 at room temperature is established by rapid quenching of the surfactant assisted sonochemically synthesized BaTiO3 after calcination for 2 h at 800 °C. The quenched BaTiO3 is stabilized to cubic phase at room temperature in contrast to the BaTiO3 obtained by normal cooling at a rate of 1 °C/min, which exists in the tetragonal phase at room temperature. BaTiO3 prepared by the same synthetic procedure but two different heat treatment methods possesses almost similar morphology (i.e.) 1-dimensional nanorod structure but with different aspect ratio. Quenching prevents the low temperature phase transformation c→t from occurring by providing a narrow window of time in which the reaction is both thermodynamically favourable and kinetically accessible.
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U2 - 10.1016/j.matlet.2016.10.048
DO - 10.1016/j.matlet.2016.10.048
M3 - Article
AN - SCOPUS:84991615339
VL - 186
SP - 305
EP - 307
JO - Materials Letters
JF - Materials Letters
SN - 0167-577X
ER -