Defects in Li4Ti5O12 induced by carbon deposition: An analysis of unidentified bands in Raman spectra

Dmitry V. Pelegov, Ralph Nicolai Nasara, Chia Hao Tu, Shih Kang Lin

研究成果: Article同行評審

2 引文 斯高帕斯(Scopus)

摘要

Lithium titanate (Li4Ti5O12, LTO) has already occupied its niche as an anode material for high-power and long-lifespan lithium batteries, but some novel directions for basic and applied research are still open. One of the most promising approaches in improving its properties, e.g., electronic conductivity and rate capability, is based on controllable defect engineering. The "defects" may be intentionally introduced into LTO via doping, surface modifications, and the synergy between them. However, the defects, which have significant effects to the electrical and electrochemical properties, are usually extremely dilute. Reliable material characterizations are essential and challenging, but the instrumental tools for revealing dilute defects are still insufficient. Herein, detailed analyses on the surface or subsurface defects of carbon-coated LTO were performed using various material characterization methods. Raman spectroscopy has been identified as a unique tool for the probing of structural defects.

原文English
頁(從 - 到)20757-20763
頁數7
期刊Physical Chemistry Chemical Physics
21
發行號37
DOIs
出版狀態Published - 2019

All Science Journal Classification (ASJC) codes

  • 物理與天文學 (全部)
  • 物理與理論化學

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