Deposition of micro-crystalline β-C3N4 films by an inductively-coupled-plasma (ICP) sputtering method

Chia Yuan Hsu, Franklin Chau Nan Hong

研究成果: Article同行評審

19 引文 斯高帕斯(Scopus)

摘要

The sputtering of a graphite target with N2 ions in an inductively-coupled plasma was employed to deposit C3N4 films in hydrogen-free atmosphere with a high degree of gas dissociation. Transmission electron diffraction patterns of the films indicate the existence of ultrafine-crystallites, structurally analogous to β-C3N4. Scanning electron micrographs show that the crystallites are less than 40 nm in diameter. From X-ray photoelectron spectroscopy (XPS) analysis it is determined that the films exhibit predominantly C - N bonding (with respect to C-to-N triple bonding) and no significant C - C bonding is observed. Besides, both the [N]/[C] ratio and the percentage of C - N bonds in the film, as determined from XPS, increase upon increasing the radio frequency power from 100 W to 600 W, with the [N]/[C] ratio attaining a value of 1.28 at 600 W. The measurement of the [N2+]/[N2] ratio by optical emission spectroscopy indicates the enhancement of the gas dissociation with increasing radio frequency power. The results suggest that β-C3N4 crystallites are favorably formed upon increasing the degree of gas dissociation.

原文English
頁(從 - 到)L675-L678
期刊Japanese Journal of Applied Physics, Part 2: Letters
37
發行號6 A
DOIs
出版狀態Published - 1998

All Science Journal Classification (ASJC) codes

  • 工程 (全部)
  • 物理與天文學(雜項)
  • 物理與天文學 (全部)

指紋

深入研究「Deposition of micro-crystalline β-C<sub>3</sub>N<sub>4</sub> films by an inductively-coupled-plasma (ICP) sputtering method」主題。共同形成了獨特的指紋。

引用此