Design and experiments of a short-mixing-length baffled microreactor and its application to microfluidic synthesis of nanoparticles

C. K. Chung, T. R. Shih, C. K. Chang, C. W. Lai, B. H. Wu

研究成果: Article同行評審

45 引文 斯高帕斯(Scopus)

摘要

Conventional microreactors with a meander micromixer were generally operated at low flow velocity together with long mixing length in nanoparticle synthesis. In this article, we demonstrate a simple micromixer with short-mixing-length baffles in order to obtain an effective mixing for a wide-range flow rate in silica nanoparticle synthesis. The planar baffled micromixer can greatly enhance the mixing behavior through the diffusion-dominant mechanism at low flow rate and the convection-dominant mechanism at high flow rate. The 3D numerical simulations and experimental confocal flow visualization evidence that a good mixing efficiency at either lower or higher flow rates can be achieved using the baffled micromixer with three mixing units with a gap size of 50μm in the 400μm wide channel. The efficient micromixer was then used for silica nanoparticle synthesis through tetraethyl orthosilicate (TEOS) solution. The size of particles can be adjusted by means of flow rate, reaction time and temperature. An average particle diameter of 250 ± 50 nm can be obtained at a low flow rate of 0.1. ml/h. At high flow rate of 35. ml/h, small particles of 88 ± 11. nm in diameter were formed at a reaction time of 12.5. min at 25°C and the size was reduced to 46 ± 7. nm at 55°C. The particle size decreased with increasing flow rate and the reaction temperature. Enhancing fluid mixing at high flow velocity with a short mixing length is beneficial for the possibility of obtaining high throughput of microreactor.

原文English
頁(從 - 到)790-798
頁數9
期刊Chemical Engineering Journal
168
發行號2
DOIs
出版狀態Published - 2011 四月 1

All Science Journal Classification (ASJC) codes

  • 化學 (全部)
  • 環境化學
  • 化學工程 (全部)
  • 工業與製造工程

指紋

深入研究「Design and experiments of a short-mixing-length baffled microreactor and its application to microfluidic synthesis of nanoparticles」主題。共同形成了獨特的指紋。

引用此