Design and validation of non-metal oxo complexes for C–H activation

Mu Jeng Cheng, Ross Fu, William A. Goddard

研究成果: Article

14 引文 斯高帕斯(Scopus)


We use our recent discovery of the reduction-coupled oxo activation (ROA) principle to design a series of organometallic molecules that activate C–H bonds through this unique proton/electron-decoupled hydrogen abstraction mechanism, in which the main group oxo moiety binds to the proton while the electron is transferred to the transition metal. Here we illustrate this general class of catalyst clusters with several examples that are validated through quantum mechanics calculations.

頁(從 - 到)1748-1750
期刊Chemical Communications
出版狀態Published - 2014 一月 21

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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