Design and validation of non-metal oxo complexes for C–H activation

Mu Jeng Cheng, Ross Fu, William A. Goddard

研究成果: Article同行評審

15 引文 斯高帕斯(Scopus)

摘要

We use our recent discovery of the reduction-coupled oxo activation (ROA) principle to design a series of organometallic molecules that activate C–H bonds through this unique proton/electron-decoupled hydrogen abstraction mechanism, in which the main group oxo moiety binds to the proton while the electron is transferred to the transition metal. Here we illustrate this general class of catalyst clusters with several examples that are validated through quantum mechanics calculations.

原文English
頁(從 - 到)1748-1750
頁數3
期刊Chemical Communications
50
發行號14
DOIs
出版狀態Published - 2014 一月 21

All Science Journal Classification (ASJC) codes

  • 催化
  • 電子、光磁材料
  • 陶瓷和複合材料
  • 化學 (全部)
  • 表面、塗料和薄膜
  • 金屬和合金
  • 材料化學

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