Diindeno[1,2,3,4-defg;1′,2′,3′,4′-mnop]chrysenes: Solution-phase synthesis and the bowl-to-bowl inversion barrier

Hung Ing Chang, Hsin Ting Huang, Cheng Hao Huang, Ming Yu Kuo, Yao-Ting Wu

研究成果: Article

28 引文 斯高帕斯(Scopus)

摘要

Diindeno[1,2,3,4-defg;1′,2′,3′,4′-mnop]chrysenes 2 were straightforwardly prepared in around 20% yield from 9,10- diarylphenanthrenes 3 by palladium-catalyzed intramolecular arylations. The bowl-to-bowl inversion barrier for buckybowl 2-iPr is predicted to be approximately 7 kcal mol -1 based on density functional theory calculations and this value is consistent with the results of a variable-temperature 1 H-NMR study.

原文English
頁(從 - 到)7241-7243
頁數3
期刊Chemical Communications
46
發行號38
DOIs
出版狀態Published - 2010 十月 14

    指紋

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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