Dinuclear oxovanadium(IV) thiolate complexes with ferromagnetically coupled interaction between vanadium centers

Yi Fang Tsai, Gui Shih Huang, Chen I. Yang, Hui Lien Tsai, Yi Hung Liu, Ting Shen Kuo, Hua Fen Hsu

研究成果: Article同行評審

7 引文 斯高帕斯(Scopus)

摘要

Two dinuclear oxovanadium(IV) thiolate complexes, [N(C5H 11)4]2-[VOL1]2 (1) and [N(C 4H9)4][(VOL2)2(μ-OCH 3)] (2) (where L1 = [(CH3)SiO(C6H 4-2-S)2]3- and L2 = [(C6H 5)PO(C6H4-2-S)2]2-), have been synthesized and characterized. The geometry of the anion in 1 can be classified to an edge-sharing bi-square-pyramid with a syn-orthogonal configuration. The one in 2 can be view as a face-sharing bioctahedron with two oxo groups in syn positions. Of note, these two complexes display intramolecular ferromagnetic interaction between two metal centers.

原文English
頁(從 - 到)10467-10469
頁數3
期刊Inorganic Chemistry
46
發行號25
DOIs
出版狀態Published - 2007 12月 10

All Science Journal Classification (ASJC) codes

  • 物理與理論化學
  • 無機化學

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