Direct separation of boron from Na- and Ca-rich matrices by sublimation for stable isotope measurement by MC-ICP-MS

Bo Shian Wang, Chen Feng You, Kuo Fang Huang, Shein Fu Wu, Suresh Kumar Aggarwal, Chuan Hsiung Chung, Pei Ying Lin

研究成果: Article

63 引文 斯高帕斯(Scopus)

摘要

An improved technique for precise and accurate determination of boron isotopic composition in Na-rich natural waters (groundwater, seawater) and marine biogenic carbonates was developed. This study used a 'micro-sublimation' technique to separate B from natural sample matrices in place of the conventional ion-exchange extraction. By adjusting analyte to appropriate pH, quantitative recovery of boron can be achieved (>98%) and the B procedural blank is limited to <8 pg. An additional mass bias effect in MC-ICP-MS was observed which could not be improved via the standard-sample-standard bracketing or the 'pseudo internal' normalization by Li. Therefore a standard other than NBS SRM 951 was used to monitor plasma condition in order to maintain analytical accuracy. An isotope cross-calibration with results from TIMS shows that the space-charge mass bias on MC-ICP-MS can be successfully corrected using off-line mathematical manipulation. Several reference materials, including the seawater IAPSO and two groundwater standards IAEA-B-2 and IAEA-B-3, were used to validate this approach. We found that the δ11B of the reference coral JCp-1 was 24.22 ± 0.28‰, corresponding to seawater pH based on the coral δ11B-pH function.

原文English
頁(從 - 到)1378-1384
頁數7
期刊Talanta
82
發行號4
DOIs
出版狀態Published - 2010 九月 15

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

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