Direct UV observation and kinetic studies of a α-alkoxy benzyloxy radical

Lu An Chen, Kuang-Sen Sung

研究成果: Article

9 引文 斯高帕斯(Scopus)

摘要

A α-alkoxy benzyloxy radical 3 was generated by laser flash photolysis of peroxyacetal 2, and its UV spectrum, decomposition pattern, reactivity with PPh3, O2, and i-PrOH, and quantum yield were explored. It was found that the radical 3 is very unstable and highly reactive and performs β-C-H scission much faster than β-C-O scission and H-abstraction.

原文English
頁(從 - 到)3370-3373
頁數4
期刊Organic Letters
11
發行號15
DOIs
出版狀態Published - 2009 八月 6

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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