摘要
Spinel LiMn2O4 thin-film cathodes were obtained by spin-coating the chitosan-containing precursor solution on a Pt-coated silicon substrate followed by a two-stage heat-treatment procedure. The LiMn2O4 film calcined at 700 °C for 1 h showed the highest Li-ion diffusion coefficient, 1.55 × 10-12 cm2 s-1 (PSCA measurement) among all calcined films. It is attributed to the larger interstitial space and better crystal perfection of LiMn2O4 film calcined at 700 °C for 1 h. Consequently, the 700 °C-calcined LiMn2O4 film exhibited the best rate performance in comparison with the ones calcined at other temperatures.
原文 | English |
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頁(從 - 到) | 179-185 |
頁數 | 7 |
期刊 | Journal of Power Sources |
卷 | 159 |
發行號 | 1 SPEC. ISS. |
DOIs | |
出版狀態 | Published - 2006 九月 13 |
All Science Journal Classification (ASJC) codes
- Renewable Energy, Sustainability and the Environment
- Energy Engineering and Power Technology
- Physical and Theoretical Chemistry
- Electrical and Electronic Engineering