Effects of porosity gradient in gas diffusion layers on performance of proton exchange membrane fuel cells

Yu Xian Huang, Chin Hsiang Cheng, Xiao Dong Wang, Jiin Yuh Jang

研究成果: Article

43 引文 斯高帕斯(Scopus)

摘要

A three-dimensional, two-phase, non-isothermal model has been developed to explore the interaction between heat and water transport in proton exchange membrane fuel cells (PEMFCs). Water condensate produced from the electrochemical reaction may accumulate in the open pores of the gas diffusion layer (GDL) and retard the oxygen transport to the catalyst sites. This study predicts the enhancement of the water transport for linear porosity gradient in the cathode GDL of a PEMFC. An optimal porosity distribution was found based on a parametric study. Results show that a optimal linear porosity gradient with e{open}1 = 0.7 and e{open}2 = 0.3 for the parallel and z-serpentine channel design leads to a maximum increase in the limiting current density from 10,696 Am-2 to 13,136 Am-2 and 14,053 Am-2 to 16,616 Am-2 at 0.49 V, respectively. On the other hand, the oxygen usage also increases from 36% to 46% for the parallel channel design and from 55% to 67% for the z-serpentine channel design. The formation of a porosity gradient in the GDL enhances the capillary diffusivity, increases the electrical conductivity, and hence, benefits the oxygen transport throughout the GDL. The present study provides a theoretical support for existing reports that a GDL with a gradient porosity improves cell performance.

原文English
頁(從 - 到)4786-4794
頁數9
期刊Energy
35
發行號12
DOIs
出版狀態Published - 2010 十二月

    指紋

All Science Journal Classification (ASJC) codes

  • Civil and Structural Engineering
  • Building and Construction
  • Pollution
  • Mechanical Engineering
  • Industrial and Manufacturing Engineering
  • Electrical and Electronic Engineering

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