Electrocatalytic determination of paraquat using a nafion film coated glassy carbon electrode

Tsai Hwa Lu, I. Wen Sun

研究成果: Article同行評審

49 引文 斯高帕斯(Scopus)

摘要

A nafion film coated glassy carbon electrode (NFGCE) was employed for the determination of paraquat. Paraquat was accumulated onto NFGCE by the cation-exchange feature of nafion at open circuit potential in basic medium followed by cathodic differential pulse voltammetric (CDPV) determination in a medium containing permanganate ions. The sensitivity for the determination of paraquat was improved through the electrocatalytic reduction of permanganate by the reduced paraquat. With 3-min accumulation, the analytical signal versus concentration dependence was linear from 1.0 to 100 ppb with a detection limit of 0.5 ppb. The interference from common metal ions was minimized by addition of ethylenediaminetetraacetate (EDTA) into the sample solution. The use of nafion also improves the resistance to interference from surfactants.

原文English
頁(從 - 到)443-451
頁數9
期刊Talanta
53
發行號2
DOIs
出版狀態Published - 2000 十一月 1

All Science Journal Classification (ASJC) codes

  • 分析化學

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