Electrochemical copolymerization of 1-naphthylamine with aniline and o-toluidine

C. Y. Chung; T. C. Wen; A. Gopalan

doi:10.1016/S0254-0584(00)00523-X

Electrochemical copolymerization of 1-naphthylamine with aniline and o-toluidine

C. Y. Chung, T. C. Wen, A. Gopalan

化學工程學系

研究成果: Article › 同行評審

22 引文斯高帕斯（Scopus）

摘要

Copolymers of 1-naphthylamine (NPA) with aniline (ANI) and o-toluidine (OT) were deposited on platinum electrode in 1M perchloric acid (HClO₄) through cyclic voltammetry. The cyclic voltammograms of the copolymer showed a dominant redox couple at a midpoint potential of ca. 0.38 V with a peak separation ranging from 40 to 100 mV. Copolymerization was found to be possible only at low NPA to ANI or OT ratio. UV-visible spectroelectrochemical study on the copolymer films prepared using different feed ratios of NPA revealed the presence of NPA units in varying proportion in the copolymer. The copolymers possess both electrochemical and spectroelectrochemical properties of PNPA and PANI/POT.

原文	English
頁（從 - 到）	148-154
頁數	7
期刊	Materials Chemistry and Physics
卷	71
發行號	2
DOIs	https://doi.org/10.1016/S0254-0584(00)00523-X
出版狀態	Published - 2001 8月 15

All Science Journal Classification (ASJC) codes

材料科學(全部)
凝聚態物理學

存取文件

10.1016/S0254-0584(00)00523-X

其它文件與鏈接

引用此

@article{67c30f4b007248ff8ba8eba35e731dfb,

title = "Electrochemical copolymerization of 1-naphthylamine with aniline and o-toluidine",

abstract = "Copolymers of 1-naphthylamine (NPA) with aniline (ANI) and o-toluidine (OT) were deposited on platinum electrode in 1M perchloric acid (HClO4) through cyclic voltammetry. The cyclic voltammograms of the copolymer showed a dominant redox couple at a midpoint potential of ca. 0.38 V with a peak separation ranging from 40 to 100 mV. Copolymerization was found to be possible only at low NPA to ANI or OT ratio. UV-visible spectroelectrochemical study on the copolymer films prepared using different feed ratios of NPA revealed the presence of NPA units in varying proportion in the copolymer. The copolymers possess both electrochemical and spectroelectrochemical properties of PNPA and PANI/POT.",

author = "Chung, {C. Y.} and Wen, {T. C.} and A. Gopalan",

note = "Funding Information: The financial support of this work, by the National Science Council of the Republic of China under contact number NSC 89-2815-C-006-088R-E and NSC 89-2214-E-006-048 are gratefully acknowledged.",

year = "2001",

month = aug,

day = "15",

doi = "10.1016/S0254-0584(00)00523-X",

language = "English",

volume = "71",

pages = "148--154",

journal = "Materials Chemistry and Physics",

issn = "0254-0584",

publisher = "Elsevier BV",

number = "2",

}

TY - JOUR

T1 - Electrochemical copolymerization of 1-naphthylamine with aniline and o-toluidine

AU - Chung, C. Y.

AU - Wen, T. C.

AU - Gopalan, A.

N1 - Funding Information: The financial support of this work, by the National Science Council of the Republic of China under contact number NSC 89-2815-C-006-088R-E and NSC 89-2214-E-006-048 are gratefully acknowledged.

PY - 2001/8/15

Y1 - 2001/8/15

N2 - Copolymers of 1-naphthylamine (NPA) with aniline (ANI) and o-toluidine (OT) were deposited on platinum electrode in 1M perchloric acid (HClO4) through cyclic voltammetry. The cyclic voltammograms of the copolymer showed a dominant redox couple at a midpoint potential of ca. 0.38 V with a peak separation ranging from 40 to 100 mV. Copolymerization was found to be possible only at low NPA to ANI or OT ratio. UV-visible spectroelectrochemical study on the copolymer films prepared using different feed ratios of NPA revealed the presence of NPA units in varying proportion in the copolymer. The copolymers possess both electrochemical and spectroelectrochemical properties of PNPA and PANI/POT.

AB - Copolymers of 1-naphthylamine (NPA) with aniline (ANI) and o-toluidine (OT) were deposited on platinum electrode in 1M perchloric acid (HClO4) through cyclic voltammetry. The cyclic voltammograms of the copolymer showed a dominant redox couple at a midpoint potential of ca. 0.38 V with a peak separation ranging from 40 to 100 mV. Copolymerization was found to be possible only at low NPA to ANI or OT ratio. UV-visible spectroelectrochemical study on the copolymer films prepared using different feed ratios of NPA revealed the presence of NPA units in varying proportion in the copolymer. The copolymers possess both electrochemical and spectroelectrochemical properties of PNPA and PANI/POT.

UR - http://www.scopus.com/inward/record.url?scp=0035881525&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035881525&partnerID=8YFLogxK

U2 - 10.1016/S0254-0584(00)00523-X

DO - 10.1016/S0254-0584(00)00523-X

M3 - Article

AN - SCOPUS:0035881525

VL - 71

SP - 148

EP - 154

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

SN - 0254-0584

IS - 2

ER -

Electrochemical copolymerization of 1-naphthylamine with aniline and o-toluidine

摘要

All Science Journal Classification (ASJC) codes

存取文件

其它文件與鏈接

指紋

引用此