Electrooxidation of benzyl alcohol at high surface area nickel (NiSx) electrodes in alkaline solution

Ten-Chin Wen, S. M. Lin, J. M. Tsai

研究成果: Article同行評審

6 引文 斯高帕斯(Scopus)

摘要

The heterogeneous catalytic redox behaviour of NiSx deposited electrodes was investigated with and without benzyl alcohol in KOH solution using cyclic voltammetry and linear sweep voltammetry. The limiting current density for benzyl alcohol oxidation on a NiSx electrode was 22 times larger than that on a polished nickel electrode. The experimental results in galvanostatic electrolysis using fractional factorial design showed that the main and interaction effects of benzyl alcohol concentration, temperature, and OH- concentration are the key variables influencing the selectivity of benzaldehyde formation during electrolysis.

原文English
頁(從 - 到)449-454
頁數6
期刊Journal of Applied Electrochemistry
24
發行號5
DOIs
出版狀態Published - 1994 五月 1

All Science Journal Classification (ASJC) codes

  • 電化學

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