Ethanol conversion to selective high-value hydrocarbons over Ni/HZSM-5 zeolite catalyst

Chun Yen Liu; Kim Struwe; Cheng Hung Lee; Haw Yeu Chuang; Jörg Sauer; Joseph Che Chin Yu; Van Huy Nguyen; Chao Wei Huang; Jeffrey C.S. Wu

doi:10.1016/j.catcom.2020.106067

Ethanol conversion to selective high-value hydrocarbons over Ni/HZSM-5 zeolite catalyst

Chun Yen Liu
, Kim Struwe
, Cheng Hung Lee
, Haw Yeu Chuang
, Jörg Sauer
, Joseph Che Chin Yu
, Van Huy Nguyen
, Chao Wei Huang
, Jeffrey C.S. Wu

化學工程學系

研究成果: Article › 同行評審

18 引文斯高帕斯（Scopus）

摘要

Bio-ethanol is a renewable fuel and can be converted to high-values chemicals. This study showed that more aromatics and gas products could be obtained at a low weight hourly space velocity (WHSV) than that at high WHSV using HZSM-5 and Ni/HZSM-5 catalysts. A low WHSV offered an increased tendency to build up aromatics and paraffins. Real bio-ethanol broth was tested and gave the similar result as pure ethanol solution. That catalysts could retain full catalytic activity after 168 h in reaction provides evidence for their long stability. This study advantageously demonstrates a promising approach to generate high-value products from bio-ethanol.

原文	English
文章編號	106067
期刊	Catalysis Communications
卷	144
DOIs	https://doi.org/10.1016/j.catcom.2020.106067
出版狀態	Published - 2020 9月

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All Science Journal Classification (ASJC) codes

催化
一般化學
製程化學與技術

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10.1016/j.catcom.2020.106067

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@article{a7fc0aa411b64bb0a449ccfd23b9d611,

title = "Ethanol conversion to selective high-value hydrocarbons over Ni/HZSM-5 zeolite catalyst",

abstract = "Bio-ethanol is a renewable fuel and can be converted to high-values chemicals. This study showed that more aromatics and gas products could be obtained at a low weight hourly space velocity (WHSV) than that at high WHSV using HZSM-5 and Ni/HZSM-5 catalysts. A low WHSV offered an increased tendency to build up aromatics and paraffins. Real bio-ethanol broth was tested and gave the similar result as pure ethanol solution. That catalysts could retain full catalytic activity after 168 h in reaction provides evidence for their long stability. This study advantageously demonstrates a promising approach to generate high-value products from bio-ethanol.",

author = "Liu, \{Chun Yen\} and Kim Struwe and Lee, \{Cheng Hung\} and Chuang, \{Haw Yeu\} and J{\"o}rg Sauer and Yu, \{Joseph Che Chin\} and Nguyen, \{Van Huy\} and Huang, \{Chao Wei\} and Wu, \{Jeffrey C.S.\}",

note = "Funding Information: The authors gratefully acknowledge the Ministry of Science and Technology (MOST), Taiwan and Green Technology Research Institute , Taiwan CPC for the financial support under grant number MOST 107-2218-E-002-005 and MEA0400002 , respectively. Funding Information: The authors gratefully acknowledge the Ministry of Science and Technology (MOST), Taiwan and Green Technology Research Institute, Taiwan CPC for the financial support under grant number MOST 107-2218-E-002-005 and MEA0400002, respectively. Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

month = sep,

doi = "10.1016/j.catcom.2020.106067",

language = "English",

volume = "144",

journal = "Catalysis Communications",

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publisher = "Elsevier BV",

}

TY - JOUR

T1 - Ethanol conversion to selective high-value hydrocarbons over Ni/HZSM-5 zeolite catalyst

AU - Liu, Chun Yen

AU - Struwe, Kim

AU - Lee, Cheng Hung

AU - Chuang, Haw Yeu

AU - Sauer, Jörg

AU - Yu, Joseph Che Chin

AU - Nguyen, Van Huy

AU - Huang, Chao Wei

AU - Wu, Jeffrey C.S.

N1 - Funding Information: The authors gratefully acknowledge the Ministry of Science and Technology (MOST), Taiwan and Green Technology Research Institute , Taiwan CPC for the financial support under grant number MOST 107-2218-E-002-005 and MEA0400002 , respectively. Funding Information: The authors gratefully acknowledge the Ministry of Science and Technology (MOST), Taiwan and Green Technology Research Institute, Taiwan CPC for the financial support under grant number MOST 107-2218-E-002-005 and MEA0400002, respectively. Publisher Copyright: © 2020 Elsevier B.V.

PY - 2020/9

Y1 - 2020/9

N2 - Bio-ethanol is a renewable fuel and can be converted to high-values chemicals. This study showed that more aromatics and gas products could be obtained at a low weight hourly space velocity (WHSV) than that at high WHSV using HZSM-5 and Ni/HZSM-5 catalysts. A low WHSV offered an increased tendency to build up aromatics and paraffins. Real bio-ethanol broth was tested and gave the similar result as pure ethanol solution. That catalysts could retain full catalytic activity after 168 h in reaction provides evidence for their long stability. This study advantageously demonstrates a promising approach to generate high-value products from bio-ethanol.

AB - Bio-ethanol is a renewable fuel and can be converted to high-values chemicals. This study showed that more aromatics and gas products could be obtained at a low weight hourly space velocity (WHSV) than that at high WHSV using HZSM-5 and Ni/HZSM-5 catalysts. A low WHSV offered an increased tendency to build up aromatics and paraffins. Real bio-ethanol broth was tested and gave the similar result as pure ethanol solution. That catalysts could retain full catalytic activity after 168 h in reaction provides evidence for their long stability. This study advantageously demonstrates a promising approach to generate high-value products from bio-ethanol.

UR - https://www.scopus.com/pages/publications/85086478827

UR - https://www.scopus.com/pages/publications/85086478827#tab=citedBy

U2 - 10.1016/j.catcom.2020.106067

DO - 10.1016/j.catcom.2020.106067

M3 - Article

AN - SCOPUS:85086478827

SN - 1566-7367

VL - 144

JO - Catalysis Communications

JF - Catalysis Communications

M1 - 106067

ER -

Ethanol conversion to selective high-value hydrocarbons over Ni/HZSM-5 zeolite catalyst

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