Fabrication and characterization of a novel inclusion complex of chiral monomer derived from (+)-camphor with β-cyclodextrins

Jui Hsiang Liu, Hsien Jung Hung, Akira Harada

研究成果: Article同行評審

8 引文 斯高帕斯(Scopus)

摘要

In order to develop a highly ordered polymer dopant to improve the physical properties of polymer materials for microsystems, a novel supramolecular inclusion complex (IC) of chiral bornyl 4-(6-acryloyloxyhexyloxy) phenyl4′-benzoate (BAPB) threaded with β-cyclodextrins (β-CDs) was synthesized. The inclusion complex was identified using Fourier transform infrared (FTIR), UV, 13C cross-polarization/magic-angle spinning (CP/MAS) NMR, 1H NMR, and X-ray diffraction (XRD). The construction of the fibrous self-assembled inclusion complex was confirmed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques. The highly ordered polymerized inclusion complex β-CD-BAPB revealed significant birefringence and was confirmed using polarized optical microscopy (POM). Polymerization of self-assembled nanofibrous monomers with methyl methacrylate was carried out, and the distribution of the nanofibers in the polymer matrix was confirmed using POM. This investigation demonstrates a novel method for the fabrication of polymeric nanofibers with highly ordered, self-assembled functional monomers. The polymeric nanofibers are expected to improve the physical properties of polymer films in the field of microelectric and micromachine systems (MEMS).

原文English
頁(從 - 到)7442-7449
頁數8
期刊Langmuir
24
發行號14
DOIs
出版狀態Published - 2008 七月 15

All Science Journal Classification (ASJC) codes

  • 材料科學(全部)
  • 凝聚態物理學
  • 表面和介面
  • 光譜
  • 電化學

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