Fabrication of resonance core assisted self-assembling gelators derived from cyclohexanone

Yan Song Zhang, A. V. Emelyanenko, Jui Hsiang Liu

研究成果: Article同行評審

4 引文 斯高帕斯(Scopus)

摘要

Three high-resonance core compounds, BHC-6, BHC-11 and BHC-cho, were synthesized. The morphologies of the self-assembled xerogels of the synthesized compounds were studied using SEM and TEM. The molecular interactions and the formation of asymmetric constructions were investigated using temperature-dependent 1H NMR spectroscopy and circular dichroism spectrometry, respectively. The induction of an asymmetric helical structure was further confirmed using TEM. The results show that increasing the resonance length strengthens intermolecular forces, leading to the formation of gels. A chiral environment produces a steric field effect, leading to the formation of asymmetric constructions. The interactions between functional groups were further confirmed using 2D nuclear overhauser effect spectroscopy NMR. The reversible E-Z isomerization and dimer formation of cinnamoyl derivatives were investigated using UV-vis and fluorescence spectrometry, relatively.

原文English
頁(從 - 到)444-451
頁數8
期刊Journal of the Taiwan Institute of Chemical Engineers
65
DOIs
出版狀態Published - 2016 8月 1

All Science Journal Classification (ASJC) codes

  • 化學 (全部)
  • 化學工程 (全部)

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