Glass transition and miscibility in blends of two semicrystalline polymers: Poly(aryl ether ketone) and poly(ether ether ketone)

E. M. Woo, Yi Chern Tseng

研究成果: Article同行評審

12 引文 斯高帕斯(Scopus)

摘要

Binary melt-blended mixtures of two aryl ether ketone polymers (i.e., a new poly(aryl ether ketone) (code name PK99) and poly(ether ether ketone) (PEEK), have been studied. Polymer miscibility in glassy amorphous (or melt) domains has been demonstrated for the binary blend comprising of two aryl-ether-ketone-type semicrystalline polymers. Composition-dependent, single Tg was observed within full composition range in the PK99/PEEK blends, and the narrow Tg breadth also suggests that the scale of mixing was fine and uniform. To better resolve any possible overlapping Tg's, physical aging was imposed on a comparison set of blend samples for the purpose of improving detectability of overlapped multiple transitions if existing. The result still showed one single Tg. The relative sharp Tg and lack of cloud point transition suggest that the scale of molecular intermixing is good. Phase homogeneity was further confirmed using optical and scanning electron microscopy. The X-ray diffractograms suggest that isomorphism does not exist in the PK99/PEEK blends and that the crystal forms of the respective polymers remain distinct and unchanged by the miscibility in the amorphous region.

原文English
頁(從 - 到)1485-1494
頁數10
期刊Journal of Polymer Science, Part B: Polymer Physics
37
發行號13
DOIs
出版狀態Published - 1999 7月 1

All Science Journal Classification (ASJC) codes

  • 凝聚態物理學
  • 物理與理論化學
  • 聚合物和塑料
  • 材料化學

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