High electrochemical activity of Bi2O3-based composite SOFC cathodes

Woo Chul Jung, Yun Jie Chang, Kuan Zong Fung, Sossina Haile

研究成果: Article

2 引文 (Scopus)

摘要

Due to high ionic conductivity and favorable oxygen electrocatalysis, doped Bi2O3 systems are promising candidates as solid oxide fuel cell cathode materials. Recently, several researchers reported reasonably low cathode polarization resistance by adding electronically conducting materials such as (La,Sr)MnO3 (LSM) or Ag to doped Bi2O3 compositions. Despite extensive research efforts toward maximizing cathode performance, however, the inherent catalytic activity and electrochemical reaction pathways of these promising materials remain largely unknown. Here, we prepare a symmetrical structure with identically sized Y0.5Bi1.5O3/ LSM composite electrodes on both sides of a YSZ electrolyte substrate. AC impedance spectroscopy (ACIS) measurements of electrochemical cells with varied cathode compositions reveal the important role of bismuth oxide phase for oxygen electrocatalysis. These observations aid in directing future research into the reaction pathways and the site-specific electrocatalytic activity as well as giving improved guidance for optimizing SOFC cathode structures with doped Bi2O3 compositions.

原文English
頁(從 - 到)278-282
頁數5
期刊Journal of the Korean Ceramic Society
51
發行號4
DOIs
出版狀態Published - 2014 七月 31

指紋

Solid oxide fuel cells (SOFC)
Cathodes
Composite materials
Electrocatalysis
Chemical analysis
Oxygen
Electronic guidance systems
Electrochemical cells
Ionic conductivity
Bismuth
Electrolytes
Catalyst activity
Spectroscopy
Polarization
Electrodes
Oxides
Substrates

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites

引用此文

Jung, Woo Chul ; Chang, Yun Jie ; Fung, Kuan Zong ; Haile, Sossina. / High electrochemical activity of Bi2O3-based composite SOFC cathodes. 於: Journal of the Korean Ceramic Society. 2014 ; 卷 51, 編號 4. 頁 278-282.
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High electrochemical activity of Bi2O3-based composite SOFC cathodes. / Jung, Woo Chul; Chang, Yun Jie; Fung, Kuan Zong; Haile, Sossina.

於: Journal of the Korean Ceramic Society, 卷 51, 編號 4, 31.07.2014, p. 278-282.

研究成果: Article

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