High-pressure synthesis of tantalum nitride having orthorhombic U 2S3 structure

Andreas Zerr, Gerhard Miehe, Jinwang Li, Dmytro A. Dzivenko, Vadim K. Bulatov, Heidi Höfer, Nathalie Boifan-Casanova, Michel Fialin, Gerhard Brey, Tomoaki Watanabe, Masahiro Yoshimura

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81 引文 斯高帕斯(Scopus)


Among binary compounds, there is a high potential for discovery of novel members (polymorphic phases or compounds) of the nitrides of transition metals group due to a pronounced dependence of the oxidation state of the metals (M) on pressure. The power of high pressure-high temperature (HP-HT) route for synthesis of binary nitrides has already been demonstrated by the discovery of cubic nitrides of the group 4 and 14 elements, of crystalline polymorphs of P3N5, and by reports on formation of four noble metal nitrides. It is anticipated that such HP products exhibit, in addition to enhanced elastic and mechanical behavior, other functional properties making them interesting for industrial applications. Here, HP-HT synthesis research is extended to nitrides of group 5 elements, resulting in the discovery of a novel hard tantalum nitride, exhibiting U2S3 structure: η-Ta2N3 (Pbnm, a = 8.1911 (17) Å, b = 8.1830(17) Å, c = 2.9823(3) Å). The stoichiometry is supported by two independent means, verifying that η-Ta2N3 is the first thermodynamically stable transition metal nitride with a N:M ratio exceeding 4:3. Due to its high hardness and peculiar texture (needle-like and granular crystallites), η-Ta2N3 may find practical applications as a hard fracture resistant material.

頁(從 - 到)2282-2288
期刊Advanced Functional Materials
出版狀態Published - 2009 七月 24

All Science Journal Classification (ASJC) codes

  • 化學 (全部)
  • 材料科學(全部)
  • 凝聚態物理學


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