Hydrothermal synthesis of monodisperse Ce0.5Zr 0.5O2 metastable solid solution nanocrystals

Takaaki Taniguchi, Tomoaki Watanabe, Nobuhiro Matsushita, Masahiro Yoshimura

研究成果: Article同行評審

23 引文 斯高帕斯(Scopus)


An environmentally friendly and economically efficient method has been developed to synthesize monodisperse CeO2-ZrO2 solid solution nanocrystals. In this process, the formation of oleate-stabilized Ce0.5Zr0.5O2 nanocrystals was designed to proceed through hydrolytic sol-gel condensation of metal-oleate precursors in an aqueous solution and subsequent hydrothermal growth at 200 °C for 6 h. The results showed that the 3.0-nm-sized nanocrystals possess a metastable CeO 2-ZrO2 tetragonal phase with well-designed chemical composition and are nearly monodisperse. Owing to the uniform textural and elemental properties, the products exhibit relatively high thermal stability of the metastable phase and well-defined reduction properties.

頁(從 - 到)2054-2057
期刊European Journal of Inorganic Chemistry
出版狀態Published - 2009 五月

All Science Journal Classification (ASJC) codes

  • 無機化學


深入研究「Hydrothermal synthesis of monodisperse Ce<sub>0.5</sub>Zr <sub>0.5</sub>O<sub>2</sub> metastable solid solution nanocrystals」主題。共同形成了獨特的指紋。