In situ EXAFS studies of copper on ZrO2 during catalytic hydrogenation of CO2

S. H. Liu, H. Paul Wang, H. C. Wang, Y. W. Yang

研究成果: Article同行評審

23 引文 斯高帕斯(Scopus)

摘要

Speciation of copper on ZrO2 during the catalytic hydrogenation of CO2 has been studied by in situ extended X-ray absorption fine structural (EXAFS) spectroscopy in the present work. The EXAFS data indicated that about 3.1 nearest oxygen atoms surrounded the Cu atoms with a CuO bond distance of 1.95 Å in the calcined Cu/ZrO2 catalyst. Reduction of the catalyst in hydrogen at 573 K led to a formation of CuCu (2.56 Å) bonds with a coordination number (CN) of 5.6. Mainly CO and CH3OH were generated in the hydrogenation of CO2 catalyzed by the reduced Cu/ZrO2 catalyst at 673 K. About 76% of the Cu(0) species was oxidized to Cu(I) (27%) and Cu(II) (49%) on ZrO2 during the catalytic hydrogenation process.

原文English
頁(從 - 到)373-376
頁數4
期刊Journal of Electron Spectroscopy and Related Phenomena
144-147
DOIs
出版狀態Published - 2005 6月

All Science Journal Classification (ASJC) codes

  • 電子、光磁材料
  • 輻射
  • 原子與分子物理與光學
  • 凝聚態物理學
  • 光譜
  • 物理與理論化學

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