In-situ fiber optic FTIR spectroscopy for coal liquefaction processes

Michael A. Serio; Hsisheng Teng; Kim S. Knight; Stephen C. Bates; Stuart Farquharson; Anthony S. Bonanno; Peter R. Solomon; William A. Stevenson; Mark A. Druy; Paul J. Glatkowski; James A. Harrington; Rick K. Nubling; Jack Y. Ding; Alfred G. Comolli

doi:10.1117/12.166281

In-situ fiber optic FTIR spectroscopy for coal liquefaction processes

Michael A. Serio, Hsisheng Teng, Kim S. Knight, Stephen C. Bates, Stuart Farquharson, Anthony S. Bonanno, Peter R. Solomon, William A. Stevenson, Mark A. Druy, Paul J. Glatkowski, James A. Harrington, Rick K. Nubling, Jack Y. Ding, Alfred G. Comolli

化學工程學系

研究成果: Conference article › 同行評審

6 引文斯高帕斯（Scopus）

摘要

The development of diagnostic instrumentation for monitoring coal liquefaction process streams is discussed. A sapphire optical fiber was used as an attenuated total reflectance (ATR) element in conjunction with Fourier transform infrared (FT-IR) spectrometry to probe harsh liquefaction process streams. ATR provides a short, reproducible pathlength which allows for the analysis of highly absorbing materials, such as liquid hydrocarbons, and the properties of sapphire are well suited for the analysis of high temperature and high pressure process streams. A test cell was constructed which allowed in-situ monitoring of coal liquefaction reactions at 400 degree(s)C and 3000 psig. The cell incorporated a sapphire optical fiber as an ATR sensing element which was coupled to an FT-IR spectrometer using zirconium fluoride fiber optic cables. The spectra provide qualitative information about the liquefaction process.

原文	English
頁（從 - 到）	121-131
頁數	11
期刊	Proceedings of SPIE - The International Society for Optical Engineering
卷	2069
DOIs	https://doi.org/10.1117/12.166281
出版狀態	Published - 1993 12月 31
事件	Optical Methods for Chemical Process Control 1993 - Boston, United States 持續時間: 1993 9月 7 → 1993 9月 10

All Science Journal Classification (ASJC) codes

電子、光磁材料
凝聚態物理學
電腦科學應用
應用數學
電氣與電子工程

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10.1117/12.166281

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Serio, M. A., Teng, H., Knight, K. S., Bates, S. C., Farquharson, S., Bonanno, A. S., Solomon, P. R., Stevenson, W. A., Druy, M. A., Glatkowski, P. J., Harrington, J. A., Nubling, R. K., Ding, J. Y., & Comolli, A. G. (1993). In-situ fiber optic FTIR spectroscopy for coal liquefaction processes. Proceedings of SPIE - The International Society for Optical Engineering, 2069, 121-131. https://doi.org/10.1117/12.166281

@article{3fb246e2a82e4544acc7a4ac2d2ffe99,

title = "In-situ fiber optic FTIR spectroscopy for coal liquefaction processes",

abstract = "The development of diagnostic instrumentation for monitoring coal liquefaction process streams is discussed. A sapphire optical fiber was used as an attenuated total reflectance (ATR) element in conjunction with Fourier transform infrared (FT-IR) spectrometry to probe harsh liquefaction process streams. ATR provides a short, reproducible pathlength which allows for the analysis of highly absorbing materials, such as liquid hydrocarbons, and the properties of sapphire are well suited for the analysis of high temperature and high pressure process streams. A test cell was constructed which allowed in-situ monitoring of coal liquefaction reactions at 400 degree(s)C and 3000 psig. The cell incorporated a sapphire optical fiber as an ATR sensing element which was coupled to an FT-IR spectrometer using zirconium fluoride fiber optic cables. The spectra provide qualitative information about the liquefaction process.",

author = "Serio, {Michael A.} and Hsisheng Teng and Knight, {Kim S.} and Bates, {Stephen C.} and Stuart Farquharson and Bonanno, {Anthony S.} and Solomon, {Peter R.} and Stevenson, {William A.} and Druy, {Mark A.} and Glatkowski, {Paul J.} and Harrington, {James A.} and Nubling, {Rick K.} and Ding, {Jack Y.} and Comolli, {Alfred G.}",

note = "Funding Information: This work was supported by the U.S. Department of Energy under Grant Nos. DE-FGO5-91ER8 1 15 1 and DE-FGO5-91ER81 151-MOD1, and by a subcontract from the Consolidation Coal Company under U.S. Department of Energy Contract No. DE-AC22-89PC89883. Publisher Copyright: {\textcopyright} 1993 SPIE. All rights reserved.; Optical Methods for Chemical Process Control 1993 ; Conference date: 07-09-1993 Through 10-09-1993",

year = "1993",

month = dec,

day = "31",

doi = "10.1117/12.166281",

language = "English",

volume = "2069",

pages = "121--131",

journal = "Proceedings of SPIE - The International Society for Optical Engineering",

issn = "0277-786X",

publisher = "SPIE",

}

Serio, MA, Teng, H, Knight, KS, Bates, SC, Farquharson, S, Bonanno, AS, Solomon, PR, Stevenson, WA, Druy, MA, Glatkowski, PJ, Harrington, JA, Nubling, RK, Ding, JY & Comolli, AG 1993, 'In-situ fiber optic FTIR spectroscopy for coal liquefaction processes', Proceedings of SPIE - The International Society for Optical Engineering, 卷 2069, 頁 121-131. https://doi.org/10.1117/12.166281

TY - JOUR

T1 - In-situ fiber optic FTIR spectroscopy for coal liquefaction processes

AU - Serio, Michael A.

AU - Teng, Hsisheng

AU - Knight, Kim S.

AU - Bates, Stephen C.

AU - Farquharson, Stuart

AU - Bonanno, Anthony S.

AU - Solomon, Peter R.

AU - Stevenson, William A.

AU - Druy, Mark A.

AU - Glatkowski, Paul J.

AU - Harrington, James A.

AU - Nubling, Rick K.

AU - Ding, Jack Y.

AU - Comolli, Alfred G.

N1 - Funding Information: This work was supported by the U.S. Department of Energy under Grant Nos. DE-FGO5-91ER8 1 15 1 and DE-FGO5-91ER81 151-MOD1, and by a subcontract from the Consolidation Coal Company under U.S. Department of Energy Contract No. DE-AC22-89PC89883. Publisher Copyright: © 1993 SPIE. All rights reserved.

PY - 1993/12/31

Y1 - 1993/12/31

N2 - The development of diagnostic instrumentation for monitoring coal liquefaction process streams is discussed. A sapphire optical fiber was used as an attenuated total reflectance (ATR) element in conjunction with Fourier transform infrared (FT-IR) spectrometry to probe harsh liquefaction process streams. ATR provides a short, reproducible pathlength which allows for the analysis of highly absorbing materials, such as liquid hydrocarbons, and the properties of sapphire are well suited for the analysis of high temperature and high pressure process streams. A test cell was constructed which allowed in-situ monitoring of coal liquefaction reactions at 400 degree(s)C and 3000 psig. The cell incorporated a sapphire optical fiber as an ATR sensing element which was coupled to an FT-IR spectrometer using zirconium fluoride fiber optic cables. The spectra provide qualitative information about the liquefaction process.

AB - The development of diagnostic instrumentation for monitoring coal liquefaction process streams is discussed. A sapphire optical fiber was used as an attenuated total reflectance (ATR) element in conjunction with Fourier transform infrared (FT-IR) spectrometry to probe harsh liquefaction process streams. ATR provides a short, reproducible pathlength which allows for the analysis of highly absorbing materials, such as liquid hydrocarbons, and the properties of sapphire are well suited for the analysis of high temperature and high pressure process streams. A test cell was constructed which allowed in-situ monitoring of coal liquefaction reactions at 400 degree(s)C and 3000 psig. The cell incorporated a sapphire optical fiber as an ATR sensing element which was coupled to an FT-IR spectrometer using zirconium fluoride fiber optic cables. The spectra provide qualitative information about the liquefaction process.

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U2 - 10.1117/12.166281

DO - 10.1117/12.166281

M3 - Conference article

AN - SCOPUS:83055175015

SN - 0277-786X

VL - 2069

SP - 121

EP - 131

JO - Proceedings of SPIE - The International Society for Optical Engineering

JF - Proceedings of SPIE - The International Society for Optical Engineering

T2 - Optical Methods for Chemical Process Control 1993

Y2 - 7 September 1993 through 10 September 1993

ER -

In-situ fiber optic FTIR spectroscopy for coal liquefaction processes

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