Influence of conductive nano-TiC on microstructural evolution of Si 3N4-based nanocomposites in spark plasma sintering

Ching Huan Lee, Horng Hwa Lu, Chang An Wang, Pramoda K. Nayak, Jow Lay Huang

研究成果: Article

15 引文 斯高帕斯(Scopus)

摘要

A conductive TiC nanopowder was incorporated into nanosized β-Si 3N4-based powder and consolidated by a spark plasma sintering (SPS) technique with a rapid heating process. The influence of the conductive phase on the microstructure development of the Si3N 4 matrix was demonstrated. After sintering, the conductive phase transformed into titanium oxycarbonitride. The Si3N4-based composite containing 5 wt% nano-TiCxOyNz shows a larger average grain size and aspect ratio than the monolithic Si 3N4-based ceramic. This is possibly because a leakage current hops across the conductive titanium oxycarbonitride grains and causes Joule heating during sintering. The transmission electron microscopy analysis confirmed that dissolution-reprecipitation and coalescence occur. In addition, although the increasing amount of incorporated nano-TiCxO yNz (10 and 20 wt%) decreases the electrical resistivity of the composites, the pinning effect of the titanium-based phase significantly suppresses the grain growth of Si3N4 matrix grains. β-Si3N4-based nanocomposites containing nanosized titanium oxycarbonitride were thus obtained in the present study.

原文English
頁(從 - 到)959-967
頁數9
期刊Journal of the American Ceramic Society
94
發行號3
DOIs
出版狀態Published - 2011 三月 1

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

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