Investigation on the Hydrocarbon and Oxygen-Containing Hydrocarbon Intermediates Leading to Crotonaldehyde Formation on TiO2

Jong-Liang Lin, Po Yuan Lin, Ying Chung Shih

研究成果: Article

摘要

Aldol condensation of CH3CHO, forming crotonaldehyde (2-butenal, CH3CH=CHCHO), readily occurs on TiO2 at 35 °C. At a higher coverage or at an elevated temperature, the crotonaldehyde can be oxidized to crotonate. Adsorption and thermal reactions of CH3CHBr2, BrCH2CH2Br, BrCH2CH2OH, and ClCH2CH2OH on TiO2 can produce crotonaldehyde, in contrast to CH2=CHBr. CH3CHBr2 has the highest reactivity toward the crotonaldehyde formation among the halogenated compounds studied. The pathways of CH3CHBr2 + Ti-O-Ti → CH3CHO + 2Ti-Br and BrCH2CH2Br + Ti-O-Ti → Ti-O-CH2CH2Br + Ti-Br → CH3CHO +2 Ti-Br are proposed for the reactions of CH3CHBr2 and BrCH2CH2Br. The crotonaldehyde generated from the reactions of the four halogenated compounds on TiO2 has lower C=O and C=C stretching frequencies as compared to those of the crotonaldehyde directly from its adsorption on TiO2. This result is attributed to the presence of Br or Cl atoms near the crotonaldehyde adsorption sites and the change in the Ti ionic bonding environment. In addition, photoirradiation (325 nm) on ClCH2CH2OH on TiO2 can enhance the crotonaldehyde formation.

原文English
頁(從 - 到)11290-11299
頁數10
期刊Journal of Physical Chemistry C
121
發行號21
DOIs
出版狀態Published - 2017 六月 1

指紋

2-butenal
Hydrocarbons
hydrocarbons
Oxygen
Adsorption
adsorption
oxygen
Stretching
Condensation
reactivity
condensation
Atoms
Crotonates
atoms

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

引用此文

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title = "Investigation on the Hydrocarbon and Oxygen-Containing Hydrocarbon Intermediates Leading to Crotonaldehyde Formation on TiO2",
abstract = "Aldol condensation of CH3CHO, forming crotonaldehyde (2-butenal, CH3CH=CHCHO), readily occurs on TiO2 at 35 °C. At a higher coverage or at an elevated temperature, the crotonaldehyde can be oxidized to crotonate. Adsorption and thermal reactions of CH3CHBr2, BrCH2CH2Br, BrCH2CH2OH, and ClCH2CH2OH on TiO2 can produce crotonaldehyde, in contrast to CH2=CHBr. CH3CHBr2 has the highest reactivity toward the crotonaldehyde formation among the halogenated compounds studied. The pathways of CH3CHBr2 + Ti-O-Ti → CH3CHO + 2Ti-Br and BrCH2CH2Br + Ti-O-Ti → Ti-O-CH2CH2Br + Ti-Br → CH3CHO +2 Ti-Br are proposed for the reactions of CH3CHBr2 and BrCH2CH2Br. The crotonaldehyde generated from the reactions of the four halogenated compounds on TiO2 has lower C=O and C=C stretching frequencies as compared to those of the crotonaldehyde directly from its adsorption on TiO2. This result is attributed to the presence of Br or Cl atoms near the crotonaldehyde adsorption sites and the change in the Ti ionic bonding environment. In addition, photoirradiation (325 nm) on ClCH2CH2OH on TiO2 can enhance the crotonaldehyde formation.",
author = "Jong-Liang Lin and Lin, {Po Yuan} and Shih, {Ying Chung}",
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TY - JOUR

T1 - Investigation on the Hydrocarbon and Oxygen-Containing Hydrocarbon Intermediates Leading to Crotonaldehyde Formation on TiO2

AU - Lin, Jong-Liang

AU - Lin, Po Yuan

AU - Shih, Ying Chung

PY - 2017/6/1

Y1 - 2017/6/1

N2 - Aldol condensation of CH3CHO, forming crotonaldehyde (2-butenal, CH3CH=CHCHO), readily occurs on TiO2 at 35 °C. At a higher coverage or at an elevated temperature, the crotonaldehyde can be oxidized to crotonate. Adsorption and thermal reactions of CH3CHBr2, BrCH2CH2Br, BrCH2CH2OH, and ClCH2CH2OH on TiO2 can produce crotonaldehyde, in contrast to CH2=CHBr. CH3CHBr2 has the highest reactivity toward the crotonaldehyde formation among the halogenated compounds studied. The pathways of CH3CHBr2 + Ti-O-Ti → CH3CHO + 2Ti-Br and BrCH2CH2Br + Ti-O-Ti → Ti-O-CH2CH2Br + Ti-Br → CH3CHO +2 Ti-Br are proposed for the reactions of CH3CHBr2 and BrCH2CH2Br. The crotonaldehyde generated from the reactions of the four halogenated compounds on TiO2 has lower C=O and C=C stretching frequencies as compared to those of the crotonaldehyde directly from its adsorption on TiO2. This result is attributed to the presence of Br or Cl atoms near the crotonaldehyde adsorption sites and the change in the Ti ionic bonding environment. In addition, photoirradiation (325 nm) on ClCH2CH2OH on TiO2 can enhance the crotonaldehyde formation.

AB - Aldol condensation of CH3CHO, forming crotonaldehyde (2-butenal, CH3CH=CHCHO), readily occurs on TiO2 at 35 °C. At a higher coverage or at an elevated temperature, the crotonaldehyde can be oxidized to crotonate. Adsorption and thermal reactions of CH3CHBr2, BrCH2CH2Br, BrCH2CH2OH, and ClCH2CH2OH on TiO2 can produce crotonaldehyde, in contrast to CH2=CHBr. CH3CHBr2 has the highest reactivity toward the crotonaldehyde formation among the halogenated compounds studied. The pathways of CH3CHBr2 + Ti-O-Ti → CH3CHO + 2Ti-Br and BrCH2CH2Br + Ti-O-Ti → Ti-O-CH2CH2Br + Ti-Br → CH3CHO +2 Ti-Br are proposed for the reactions of CH3CHBr2 and BrCH2CH2Br. The crotonaldehyde generated from the reactions of the four halogenated compounds on TiO2 has lower C=O and C=C stretching frequencies as compared to those of the crotonaldehyde directly from its adsorption on TiO2. This result is attributed to the presence of Br or Cl atoms near the crotonaldehyde adsorption sites and the change in the Ti ionic bonding environment. In addition, photoirradiation (325 nm) on ClCH2CH2OH on TiO2 can enhance the crotonaldehyde formation.

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