摘要
Electronic spectra are reported for the metal cluster (Te2+) and metal cluster complex (Ag+-benzene, Mg+-CO2) cations. These ions are generated by laser vaporization in a pulsed nozzle source, jet-cooled, mass-selected with a reflectron time-of-flight spectrometer, and dissociated on resonance with a tunable dye laser. Electronic excitation spectra are recorded by monitoring the appearance of the fragment-ion channel(s) as the dissociation laser is tuned through electronic and/or vibronic resonances. Analysis of these new spectra yields vibrational constants, binding energetics and evidence for new photochemistry in these novel ion systems.
原文 | English |
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頁(從 - 到) | 269-277 |
頁數 | 9 |
期刊 | Faraday Discussions |
卷 | 92 |
DOIs | |
出版狀態 | Published - 1991 |
All Science Journal Classification (ASJC) codes
- 一般醫學