Laser photodissociation spectroscopy of mass-selected metal clusters

Kenneth F. Willey, David L. Robbins, Chen Sheng Yeh, Michael A. Duncan

研究成果: Article同行評審

5 引文 斯高帕斯(Scopus)

摘要

Electronic spectra are reported for the metal cluster (Te2+) and metal cluster complex (Ag+-benzene, Mg+-CO2) cations. These ions are generated by laser vaporization in a pulsed nozzle source, jet-cooled, mass-selected with a reflectron time-of-flight spectrometer, and dissociated on resonance with a tunable dye laser. Electronic excitation spectra are recorded by monitoring the appearance of the fragment-ion channel(s) as the dissociation laser is tuned through electronic and/or vibronic resonances. Analysis of these new spectra yields vibrational constants, binding energetics and evidence for new photochemistry in these novel ion systems.

原文English
頁(從 - 到)269-277
頁數9
期刊Faraday Discussions
92
DOIs
出版狀態Published - 1991

All Science Journal Classification (ASJC) codes

  • 一般醫學

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