Low temperature deposition of diamond using chloromethane in a hot-filament chemical vapor deposition reactor

Franklin Chau Nan Hong, Jing Chuang Hsieh, Jih Jen Wu, Gou Tsau Liang, Jen Haw Hwang

研究成果: Conference article同行評審

35 引文 斯高帕斯(Scopus)

摘要

Chloromethanes (CH2Cl2, CHCl3 and CCl4) were used as carbon sources to grow diamond at low temperature (from 380 °C to 700 °C). In comparison with methane, which is inefficient at growing diamond below 600 °C, chloromethane was quite suitable for the growth of diamond films at low temperature. Diamond growth was possible even at 380 °C, which was the lowest temperature possible in the system utilized here, using CCl4 reactant. Scanning electron micrographs, X-ray diffraction patterns and Raman spectra confirmed the presence of diamond crystallites. However, the growth rate at 380 °C was only 0.05 μm h-1. Improved growth rates were achieved with hydrogen passing through the hot-filament and carbon source gas bypassing the filament (bypass configuration). The growth rate of diamond was indeed enhanced very significantly using chloromethane in the bypass configuration. However, problems such as non-uniform growth and a narrow range of possible growth parameters arose using the bypass configuration. In contrast, the growth rate was not enhanced by using methane in the bypass configuration. The advantages of chloromethane are demonstrated. Possible reasons for such advantages are also discussed.

原文English
頁(從 - 到)365-372
頁數8
期刊Diamond and Related Materials
2
發行號2 -4 pt 1
出版狀態Published - 1993 1月 1
事件Proceedings of the 3rd International Conference on the New Diamond Science and Technology (ICNDST-3) jointly with 3rd European Conference on Diamond, Diamond-like and Related Coatings (DF '92). Part 2 (of 2) - Heidelberg, Ger
持續時間: 1992 8月 311992 9月 4

All Science Journal Classification (ASJC) codes

  • 電子、光磁材料
  • 化學 (全部)
  • 機械工業
  • 材料化學
  • 電氣與電子工程

指紋

深入研究「Low temperature deposition of diamond using chloromethane in a hot-filament chemical vapor deposition reactor」主題。共同形成了獨特的指紋。

引用此