TY - JOUR
T1 - Manganese(III) Acetate Initiated Oxidative Free Radical Reaction between 2-Anilino-1,4-naphthoquinones and Diethyl Malonate
AU - Chuang, Che Ping
AU - Wang, Sheow Fong
PY - 1997
Y1 - 1997
N2 - A free radical reaction between 2-anilino-1,4-naphthoquinones and diethyl malonate initiated by manganese (III) acetate is described. This reaction provides a novel method for the synthesis of 5,6,11,12-tetrahydro-6,11-dioxo-benzo[b]acridines. With a meta substituent on the anilino group, this reaction shows poor to high regioselectivity depending on the steric effect of the substituents on the anilino group and malonate.
AB - A free radical reaction between 2-anilino-1,4-naphthoquinones and diethyl malonate initiated by manganese (III) acetate is described. This reaction provides a novel method for the synthesis of 5,6,11,12-tetrahydro-6,11-dioxo-benzo[b]acridines. With a meta substituent on the anilino group, this reaction shows poor to high regioselectivity depending on the steric effect of the substituents on the anilino group and malonate.
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U2 - 10.1002/jccs.199700042
DO - 10.1002/jccs.199700042
M3 - Article
AN - SCOPUS:0001633814
SN - 0009-4536
VL - 44
SP - 271
EP - 277
JO - Journal of the Chinese Chemical Society
JF - Journal of the Chinese Chemical Society
IS - 3
ER -