Mechanochemical synthesis of Si/Cu3Si-based composite as negative electrode materials for lithium ion battery

Shang Chieh Hou, Tsan Yao Chen, Yu Hsien Wu, Hung Yuan Chen, Xin Dian Lin, Yu Qi Chen, Jow Lay Huang, Chia Chin Chang

研究成果: Article

2 引文 斯高帕斯(Scopus)

摘要

Mechanochemical synthesis of Si/Cu3Si-based composite as negative electrode materials for lithium ion battery is investigated. Results indicate that CuO is decomposed and alloyed with Si forming amorphous Cu-Si solid solution due to high energy impacting during high energy mechanical milling (HEMM). Upon carbonization at 800 °C, heating energy induces Cu3Si to crystallize in nanocrystalline/amorphous Si-rich matrix enhancing composite rigidity and conductivity. In addition, residual carbon formed on outside surface of composite powder as a buff space further alleviates volume change upon lithiation/delithiation. Thus, coin cell made of C-coated Si/Cu3Si-based composite as negative electrode (active materials loading, 2.3 mg cm−2) conducted at 100 mA g−1 performs the initial charge capacity of 1812 mAh g−1 (4.08 mAh cm−2) columbic efficiency of 83.7% and retained charge capacity of 1470 mAh g−1 (3.31 mAh cm−2) at the end of the 100th cycle, opening a promised window as negative electrode materials for lithium ion batteries.

原文English
文章編號12695
期刊Scientific reports
8
發行號1
DOIs
出版狀態Published - 2018 十二月 1

All Science Journal Classification (ASJC) codes

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