[Mn3O(O2CPh)6(py)2] 2(4,4′-bpy) and [Mn9O7(O2CC6H 4-p-OMe)13(4,4′-bpy)]2: New multinuclear manganese complexes

Hilary J. Eppley, Nadine DeVries, Sheyi Wang, Sheila M. Aubin, Hui Lien Tsai, Kirsten Folting, David N. Hendrickson, George Christou

研究成果: Article

29 引文 斯高帕斯(Scopus)

摘要

The synthesis, X-ray crystal structures and magnetic properties of two new types of dimers of multinuclear manganese aggregates are described. [Mn3O(O2CPh)6(py)2] 2(4,4′-bpy) is prepared from the reaction of the trinuclear starting material [Mn3O(O2CPh)6(py)2(H2O)] with 4,4′-bipyridine. This compound can be described as a dimer of trinuclear units and has been characterized crystallographically as part of a unit cell which also contains a monomeric, trinuclear species. Dimers of enneanuclear manganese complexes linked by two bifunctional units (4,4′-bipyridine or trans-1,2-bis(4-pyridylethene)) may be prepared from the tetranuclear starting material, (nBu4N) [Mn4O2-(O2CR)9(H2O)], where R=Ph or C6H4-p-OMe. The new octadecanuclear complex [Mn9O7(O2CC6H 4-p-OMe)13(4,4′-bpy)]2 has been structurally characterized. This complex shows magnetic behavior which can be fit by considering only magnetic interactions within the individual Mn9O7 units.

原文English
頁(從 - 到)323-340
頁數18
期刊Inorganica Chimica Acta
263
發行號1-2
出版狀態Published - 1997 十月 15

    指紋

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

引用此

Eppley, H. J., DeVries, N., Wang, S., Aubin, S. M., Tsai, H. L., Folting, K., Hendrickson, D. N., & Christou, G. (1997). [Mn3O(O2CPh)6(py)2] 2(4,4′-bpy) and [Mn9O7(O2CC6H 4-p-OMe)13(4,4′-bpy)]2: New multinuclear manganese complexes. Inorganica Chimica Acta, 263(1-2), 323-340.