Molecular architecture based on manganese triangles: Monomer, dimer, and one-dimensional polymer

Chen I. Yang, Po Yeng Feng, Yen Tung Chen, Yu Jhe Tsai, Gene Hsiang Lee, Hui Lien Tsai

研究成果: Article

13 引文 (Scopus)

摘要

The reaction of salicylaldoxime (H2salox) with MnCl 2·4H2O and NEt4OH in MeOH affords the trinuclear manganese complex (NEt4)[Mn3O(salox) 3(MeOH)2(H2O)2Cl2] ·MeOH (1·MeOH). A similar reaction of 1·MeOH was carried out using MnBr2·4H2O to obtain the hexanuclear manganese complex (NEt4)3{NaBr2[Mn 3O(salox)3(H2O)4Br2] 2} (2). The reaction of 2-hydroxy-4-methoxybenzaldehyde oxime (4-MeO-H2salox) and Mn(ClO4)2·6H 2O with 1,2-di(4-pyridyl)ethylene (dpe) in MeOH/DMF mixtures yields the one-dimensional complex {[Mn3O(4-MeOsalox)3(dpe) 1.5(DMF)2(H2O)](ClO4)}n (3·DMF·H2O). Complex 1·MeOH shows a typical structure of a [MnIII3O]7+ core, and complex 2 contains a dimer [MnIII3O]7+ core connected by a Na+ ion. Complex 3 has a one-dimensional chain structure constructed from [MnIII3O]7+ units linked by dpe ligands. Magnetic analysis shows that all three complexes exhibit antiferromagnetic interactions between the MnIII ions.

原文English
頁(從 - 到)3265-3271
頁數7
期刊Polyhedron
30
發行號18
DOIs
出版狀態Published - 2011 十一月 28

指紋

Manganese
triangles
Dimers
manganese
Polymers
monomers
Monomers
dimers
Ions
Oximes
polymers
Ethylene
Ligands
ions
ethylene
ligands
perchlorate
interactions
2-hydroxy-4-methoxybenzaldehyde
salicylaldoxime

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

引用此文

Yang, Chen I. ; Feng, Po Yeng ; Chen, Yen Tung ; Tsai, Yu Jhe ; Lee, Gene Hsiang ; Tsai, Hui Lien. / Molecular architecture based on manganese triangles : Monomer, dimer, and one-dimensional polymer. 於: Polyhedron. 2011 ; 卷 30, 編號 18. 頁 3265-3271.
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abstract = "The reaction of salicylaldoxime (H2salox) with MnCl 2·4H2O and NEt4OH in MeOH affords the trinuclear manganese complex (NEt4)[Mn3O(salox) 3(MeOH)2(H2O)2Cl2] ·MeOH (1·MeOH). A similar reaction of 1·MeOH was carried out using MnBr2·4H2O to obtain the hexanuclear manganese complex (NEt4)3{NaBr2[Mn 3O(salox)3(H2O)4Br2] 2} (2). The reaction of 2-hydroxy-4-methoxybenzaldehyde oxime (4-MeO-H2salox) and Mn(ClO4)2·6H 2O with 1,2-di(4-pyridyl)ethylene (dpe) in MeOH/DMF mixtures yields the one-dimensional complex {[Mn3O(4-MeOsalox)3(dpe) 1.5(DMF)2(H2O)](ClO4)}n (3·DMF·H2O). Complex 1·MeOH shows a typical structure of a [MnIII3O]7+ core, and complex 2 contains a dimer [MnIII3O]7+ core connected by a Na+ ion. Complex 3 has a one-dimensional chain structure constructed from [MnIII3O]7+ units linked by dpe ligands. Magnetic analysis shows that all three complexes exhibit antiferromagnetic interactions between the MnIII ions.",
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Molecular architecture based on manganese triangles : Monomer, dimer, and one-dimensional polymer. / Yang, Chen I.; Feng, Po Yeng; Chen, Yen Tung; Tsai, Yu Jhe; Lee, Gene Hsiang; Tsai, Hui Lien.

於: Polyhedron, 卷 30, 編號 18, 28.11.2011, p. 3265-3271.

研究成果: Article

TY - JOUR

T1 - Molecular architecture based on manganese triangles

T2 - Monomer, dimer, and one-dimensional polymer

AU - Yang, Chen I.

AU - Feng, Po Yeng

AU - Chen, Yen Tung

AU - Tsai, Yu Jhe

AU - Lee, Gene Hsiang

AU - Tsai, Hui Lien

PY - 2011/11/28

Y1 - 2011/11/28

N2 - The reaction of salicylaldoxime (H2salox) with MnCl 2·4H2O and NEt4OH in MeOH affords the trinuclear manganese complex (NEt4)[Mn3O(salox) 3(MeOH)2(H2O)2Cl2] ·MeOH (1·MeOH). A similar reaction of 1·MeOH was carried out using MnBr2·4H2O to obtain the hexanuclear manganese complex (NEt4)3{NaBr2[Mn 3O(salox)3(H2O)4Br2] 2} (2). The reaction of 2-hydroxy-4-methoxybenzaldehyde oxime (4-MeO-H2salox) and Mn(ClO4)2·6H 2O with 1,2-di(4-pyridyl)ethylene (dpe) in MeOH/DMF mixtures yields the one-dimensional complex {[Mn3O(4-MeOsalox)3(dpe) 1.5(DMF)2(H2O)](ClO4)}n (3·DMF·H2O). Complex 1·MeOH shows a typical structure of a [MnIII3O]7+ core, and complex 2 contains a dimer [MnIII3O]7+ core connected by a Na+ ion. Complex 3 has a one-dimensional chain structure constructed from [MnIII3O]7+ units linked by dpe ligands. Magnetic analysis shows that all three complexes exhibit antiferromagnetic interactions between the MnIII ions.

AB - The reaction of salicylaldoxime (H2salox) with MnCl 2·4H2O and NEt4OH in MeOH affords the trinuclear manganese complex (NEt4)[Mn3O(salox) 3(MeOH)2(H2O)2Cl2] ·MeOH (1·MeOH). A similar reaction of 1·MeOH was carried out using MnBr2·4H2O to obtain the hexanuclear manganese complex (NEt4)3{NaBr2[Mn 3O(salox)3(H2O)4Br2] 2} (2). The reaction of 2-hydroxy-4-methoxybenzaldehyde oxime (4-MeO-H2salox) and Mn(ClO4)2·6H 2O with 1,2-di(4-pyridyl)ethylene (dpe) in MeOH/DMF mixtures yields the one-dimensional complex {[Mn3O(4-MeOsalox)3(dpe) 1.5(DMF)2(H2O)](ClO4)}n (3·DMF·H2O). Complex 1·MeOH shows a typical structure of a [MnIII3O]7+ core, and complex 2 contains a dimer [MnIII3O]7+ core connected by a Na+ ion. Complex 3 has a one-dimensional chain structure constructed from [MnIII3O]7+ units linked by dpe ligands. Magnetic analysis shows that all three complexes exhibit antiferromagnetic interactions between the MnIII ions.

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SP - 3265

EP - 3271

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 18

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