Nonequilibrium and nonadiabatic effects on excited state electron transfer reactions in solution

Shyh Gang Su, John D. Simon

研究成果: Article同行評審

22 引文 斯高帕斯(Scopus)

摘要

Picosecond emission spectroscopy is used to examine the intramolecular charge transfer reaction of N,N-dimethylaminophenyl sulphone in alcohol solution. The effects of nonequilibrium distributions on the reaction surface as well as nonadiabatic effects arising from the time scale of the reactive process and solvent diffusion are discussed. The implications of these data on the motion along the reaction potential energy surface are described.

原文English
頁(從 - 到)423-428
頁數6
期刊Chemical Physics Letters
158
發行號5
DOIs
出版狀態Published - 1989 六月 16

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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