Nonequilibrium and nonadiabatic effects on excited state electron transfer reactions in solution

Shyh Gang Su; John D. Simon

doi:10.1016/0009-2614(89)87364-6

Nonequilibrium and nonadiabatic effects on excited state electron transfer reactions in solution

Shyh Gang Su, John D. Simon

化學系

研究成果: Article › 同行評審

22 引文斯高帕斯（Scopus）

摘要

Picosecond emission spectroscopy is used to examine the intramolecular charge transfer reaction of N,N-dimethylaminophenyl sulphone in alcohol solution. The effects of nonequilibrium distributions on the reaction surface as well as nonadiabatic effects arising from the time scale of the reactive process and solvent diffusion are discussed. The implications of these data on the motion along the reaction potential energy surface are described.

原文	English
頁（從 - 到）	423-428
頁數	6
期刊	Chemical Physics Letters
卷	158
發行號	5
DOIs	https://doi.org/10.1016/0009-2614(89)87364-6
出版狀態	Published - 1989 六月 16

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(89)87364-6

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引用此

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