Observation of the shallow 2 Π 1 state of NaH

Chia Ching Chu, Hsien Yu Huang, Hsiang Chin Lin, Yi Hsiang Hsiao, Thou-Jen Whang, Chin-Chun Tsai

研究成果: Article

摘要

The 2 1 Π state of NaH has been observed up to the last bound vibrational level using pulsed optical-optical double resonance fluorescence depletion spectroscopy. A total of 20 rovibrational energy levels (v = 2-4 and J = 1-9) were assigned to this electronic state by means of comparing the successive rovibrational spectra to the eigenvalues of the ab initio potential energy curve. The decrease of background fluorescence near the atomic asymptotic limit Na(3d) + H(1s) is an indication of reaching the dissociation limit of the NaH 2 1 Π state. Unobserved rovibrational levels (v = 0 and 1) are due to poor Franck-Condon overlap of 2 1 Π ← A 1 Σ + transition within the accessible rovibrational levels of intermediate A 1 Σ + state of this work.

原文English
文章編號024303
期刊Journal of Chemical Physics
150
發行號2
DOIs
出版狀態Published - 2019 一月 14

指紋

Fluorescence spectroscopy
Electronic states
Potential energy
Electron energy levels
Fluorescence
resonance fluorescence
indication
depletion
eigenvalues
energy levels
potential energy
dissociation
fluorescence
curves
electronics
spectroscopy

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

引用此文

Chu, Chia Ching ; Huang, Hsien Yu ; Lin, Hsiang Chin ; Hsiao, Yi Hsiang ; Whang, Thou-Jen ; Tsai, Chin-Chun. / Observation of the shallow 2 Π 1 state of NaH. 於: Journal of Chemical Physics. 2019 ; 卷 150, 編號 2.
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abstract = "The 2 1 Π state of NaH has been observed up to the last bound vibrational level using pulsed optical-optical double resonance fluorescence depletion spectroscopy. A total of 20 rovibrational energy levels (v = 2-4 and J = 1-9) were assigned to this electronic state by means of comparing the successive rovibrational spectra to the eigenvalues of the ab initio potential energy curve. The decrease of background fluorescence near the atomic asymptotic limit Na(3d) + H(1s) is an indication of reaching the dissociation limit of the NaH 2 1 Π state. Unobserved rovibrational levels (v = 0 and 1) are due to poor Franck-Condon overlap of 2 1 Π ← A 1 Σ + transition within the accessible rovibrational levels of intermediate A 1 Σ + state of this work.",
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Observation of the shallow 2 Π 1 state of NaH. / Chu, Chia Ching; Huang, Hsien Yu; Lin, Hsiang Chin; Hsiao, Yi Hsiang; Whang, Thou-Jen; Tsai, Chin-Chun.

於: Journal of Chemical Physics, 卷 150, 編號 2, 024303, 14.01.2019.

研究成果: Article

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T1 - Observation of the shallow 2 Π 1 state of NaH

AU - Chu, Chia Ching

AU - Huang, Hsien Yu

AU - Lin, Hsiang Chin

AU - Hsiao, Yi Hsiang

AU - Whang, Thou-Jen

AU - Tsai, Chin-Chun

PY - 2019/1/14

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AB - The 2 1 Π state of NaH has been observed up to the last bound vibrational level using pulsed optical-optical double resonance fluorescence depletion spectroscopy. A total of 20 rovibrational energy levels (v = 2-4 and J = 1-9) were assigned to this electronic state by means of comparing the successive rovibrational spectra to the eigenvalues of the ab initio potential energy curve. The decrease of background fluorescence near the atomic asymptotic limit Na(3d) + H(1s) is an indication of reaching the dissociation limit of the NaH 2 1 Π state. Unobserved rovibrational levels (v = 0 and 1) are due to poor Franck-Condon overlap of 2 1 Π ← A 1 Σ + transition within the accessible rovibrational levels of intermediate A 1 Σ + state of this work.

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