Observations on PVP-protected noble metallic nanoparticle deposits upon heating via in situ synchrotron radiation X-ray diffraction

Jenn Ming Song, Guan Di Chiou, Wei Ting Chen, Shih Yun Chen, Tzu Hsuan Kao, In-Gann Chen, Hsin Yi Lee

研究成果: Article

5 引文 (Scopus)

摘要

Through monitoring the evolution of the X-ray diffraction peaks, the phase transformation of PVP-protected Ag and Au nanoparticle deposits (NPDs) on electronic substrates of Cu and Ni upon heating in air was investigated via in situ synchrotron radiation X-ray diffraction. With an increasing temperature, the broad diffraction peak of nano-sized Ag and Au particles with the original average diameters of 4.2 nm and 9.6 nm, respectively, became sharp because of particle coarsening and coalescence. Complex phase transitions among Au, Cu, AuCu3 and CuOx were observed, mainly due to the negative enthalpy of mixing between Au and Cu. The interactions between NPDs and the substrates affected the shift of diffraction peaks to lower angles, caused by thermal expansion and also the temperature for the oxide formation. Compared to Au, Ag NPDs did not form intermetallic compounds with Cu and the formation of copper oxides can also be retarded mainly due to the phase separation feature of the Ag-Cu system.

原文English
頁(從 - 到)5099-5104
頁數6
期刊Physical Chemistry Chemical Physics
13
發行號11
DOIs
出版狀態Published - 2011 三月 21

指紋

Synchrotron radiation
synchrotron radiation
Deposits
deposits
Nanoparticles
Heating
X ray diffraction
nanoparticles
heating
Diffraction
Phase transitions
diffraction
x rays
Copper oxides
Coarsening
Substrates
Coalescence
Phase separation
Oxides
Particles (particulate matter)

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

引用此文

Song, Jenn Ming ; Chiou, Guan Di ; Chen, Wei Ting ; Chen, Shih Yun ; Kao, Tzu Hsuan ; Chen, In-Gann ; Lee, Hsin Yi. / Observations on PVP-protected noble metallic nanoparticle deposits upon heating via in situ synchrotron radiation X-ray diffraction. 於: Physical Chemistry Chemical Physics. 2011 ; 卷 13, 編號 11. 頁 5099-5104.
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Observations on PVP-protected noble metallic nanoparticle deposits upon heating via in situ synchrotron radiation X-ray diffraction. / Song, Jenn Ming; Chiou, Guan Di; Chen, Wei Ting; Chen, Shih Yun; Kao, Tzu Hsuan; Chen, In-Gann; Lee, Hsin Yi.

於: Physical Chemistry Chemical Physics, 卷 13, 編號 11, 21.03.2011, p. 5099-5104.

研究成果: Article

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