One dimensional coordination polymer of cadmiym(II) with thiocyanate bridge: Synthesis, characterization and molecular properties

Abhijit Pal, Merry Mitra, Bhaskar Biswas, Siang Hua Huang, Hui Lien Tsai, Rajarshi Ghosh

研究成果: Article同行評審

1 引文 斯高帕斯(Scopus)

摘要

A one dimensional (1D) coordination polymer [Cd(bzpy)(NCS)(SCN)] n (1) is synthesized and X-ray crystallo-graphically characterized. 1 crystallizes in P-1 space group and the asymmetric unit contains one crystallographically independent cadmium(II) centre, one ligand (bzpy) and four thiocyanate ions. Cadmium(I) is surrounded by one nitrogen and one oxygen atom from the benzoyl pyridine moiety. Cadmium(I) here lies in a distorted octahedral environment with the CdN3S20 chromophore. Thermogravimetry reveals that 1 is thermally stable up to about 130 °C. After excitation at 350 nm, it gives strong emission in dimethylformamide (DMF) at 417 nm with a hump at 545 nm due to π-π* transition.

原文English
頁(從 - 到)801-805
頁數5
期刊Journal of the Indian Chemical Society
90
發行號6
出版狀態Published - 2013 6月

All Science Journal Classification (ASJC) codes

  • 藥物發現
  • 物理與理論化學
  • 有機化學
  • 無機化學
  • 電化學

指紋

深入研究「One dimensional coordination polymer of cadmiym(II) with thiocyanate bridge: Synthesis, characterization and molecular properties」主題。共同形成了獨特的指紋。

引用此