Optimization of the dye-sensitized solar cell performance by mechanical compression

Teen Hang Meen, Jenn Kai Tsai, Yu Shin Tu, Tian Chiuan Wu, Wen Dung Hsu, Shoou Jinn Chang

研究成果: Article同行評審

13 引文 斯高帕斯(Scopus)

摘要

In this study, the P25 titanium dioxide (TiO2) nanoparticle (NP) thin film was coated on the fluorine-doped tin oxide (FTO) glass substrate by a doctor blade method. The film then compressed mechanically to be the photoanode of dye-sensitized solar cells (DSSCs). Various compression pressures on TiO2 NP film were tested to optimize the performance of DSSCs. The mechanical compression reduces TiO2 inter-particle distance improving the electron transport efficiency. The UV–vis spectrophotometer and electrochemical impedance spectroscopy (EIS) were employed to quantify the light-harvesting efficiency and the charge transport impedance at various interfaces in DSSC, respectively. The incident photon-to-current conversion efficiency was also monitored. The results show that when the DSSC fabricated by the TiO2 NP thin film compressed at pressure of 279 kg/cm2, the minimum resistance of 9.38 Ω at dye/TiO2 NP/electrolyte interfaces, the maximum short-circuit photocurrent density of 15.11 mA/cm2, and the photoelectric conversion efficiency of 5.94% were observed. Compared to the DSSC fabricated by the non-compression of TiO2 NP thin film, the overall conversion efficiency is improved over 19.5%. The study proves that under suitable compression pressure the performance of DSSC can be optimized.

原文English
文章編號523
期刊Nanoscale Research Letters
9
發行號1
DOIs
出版狀態Published - 2014

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics

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