Oxidative free radical reactions between 2-benzyl-1,4-naphthoquinones and β-dicarbonyl compounds

An I. Tsai, Yi Lung Wu, Che Ping Chuang

研究成果: Article同行評審

30 引文 斯高帕斯(Scopus)

摘要

Oxidative free radical reactions between 2-benzyl-1,4-naphthoquinones and β-dicarbonyl compounds are described. Electrophilic carbon-centered radicals produced by the manganese(III) acetate or cerium(IV) ammonium nitrate oxidation of β-dicarbonyl compounds undergo efficient addition to a C-C double bond of quinone ring. This free radical reaction provides a novel method for the synthesis of naphthacene-5,12-diones.

原文English
頁(從 - 到)7829-7837
頁數9
期刊Tetrahedron
57
發行號37
DOIs
出版狀態Published - 2001 9月 10

All Science Journal Classification (ASJC) codes

  • 生物化學
  • 藥物發現
  • 有機化學

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